Publications by authors named "Andrea L Rizzo"

Measuring the carbon stable isotope ratio (C/C, expressed as δC) in geogenic CO fluids is a crucial geochemical tool for studying Earth's degassing. Carbon stable isotope analysis is traditionally performed by bulk mass spectrometry. Although Raman spectroscopy distinguishes CO and CO isotopologue bands in spectra, using this technique to determine CO isotopic signature has been challenging.

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Subduction transports volatiles between Earth's mantle, crust, and atmosphere, ultimately creating a habitable Earth. We use isotopes to track carbon from subduction to outgassing along the Aleutian-Alaska Arc. We find substantial along-strike variations in the isotopic composition of volcanic gases, explained by different recycling efficiencies of subducting carbon to the atmosphere via arc volcanism and modulated by subduction character.

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Iron is an essential nutrient that regulates productivity in ~30% of the ocean. Compared with deep (>2000 meter) hydrothermal activity at mid-ocean ridges that provide iron to the ocean's interior, shallow (<500 meter) hydrothermal fluids are likely to influence the surface's ecosystem. However, their effect is unknown.

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Submarine volcanism represents ~80% of the volcanic activity on Earth and is an important source of mantle-derived gases. These gases are of basic importance for the comprehension of mantle characteristics in areas where subaerial volcanism is missing or strongly modified by the presence of crustal/atmospheric components. Though, the study of submarine volcanism remains a challenge due to their hazardousness and sea-depth.

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We report evidences of active seabed doming and gas discharge few kilometers offshore from the Naples harbor (Italy). Pockmarks, mounds, and craters characterize the seabed. These morphologies represent the top of shallow crustal structures including pagodas, faults and folds affecting the present-day seabed.

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