A super activated carbon (SAC) was produced by KOH-activation of a biomass waste for paracetamol (PCT) adsorption from aqueous solution and for adsorption-thermal regeneration cycles. The SAC and the regenerated SAC after five adsorption-regeneration cycles (RSAC-5th) were fully characterized by several techniques. The N physisorption showed that the S values of the SAC and RSAC-5th are remarkably different, being 2794 m² g and 889 m² g, respectively.
View Article and Find Full Text PDFThe present work reports the preparation of CO-activated carbon (AC) using Stevia rebaudiana (Bertoni) residue as a new carbon precursor. The experimental parameters were optimized via chemometrics tools to obtain an AC with high BET surface area (S). The found optimum condition was: activation temperature of 900 °C, CO flow of 165 cm g and activation time of 60 min, providing an AC with S of 874 m g.
View Article and Find Full Text PDFThe present work reports the development and application of bismuth-film electrode (BiFE), obtained by in situ method on the pencil-lead graphite surface, for simultaneous Cd(II) and Pb(II) determination at trace levels, as alternative to replace the mercury-film electrodes. Experimental factors, deposition time ( ), deposition potential ( ), and Bi(III) concentration ( ), were investigated by applying a 2 factorial design using 0.10 mol/L acetate buffer solution (pH 4.
View Article and Find Full Text PDFIn this study, the biosorption properties of Jatoba (Hymenaea courbaril) fruit shell for removal of Pb(II) and Cd(II) ions from aqueous solutions, and its potential as a low-cost biosorbent for water treatment, were investigated. The Jatoba fruit shell (JB) was subjected to different treatments with heated water (JB) and sodium hydroxide (JB) to modify its surfaces and improve its adsorption properties. The chemical modification of the surfaces of the resulting materials was confirmed by analyzing the compositions and structural features of the raw material and the chemically treated materials using SEM, FTIR, C NMR, and pH.
View Article and Find Full Text PDFThe present work reports the preparation of activated carbon fibers (ACFs) from pineapple plant leaves, and its application on caffeine (CFN) removal from aqueous solution. The preparation procedure was carried out using the HPO as activating agent and slow pyrolysis under N atmosphere. The characterization of materials was performed from the N adsorption and desorption isotherms, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Raman spectroscopy, Boehm titration and pH method.
View Article and Find Full Text PDFActivated carbons were prepared from flamboyant pods by NaOH activation at three different NaOH:char ratios: 1:1 (AC-1), 2:1 (AC-2), and 3:1 (AC-3). The properties of these carbons, including BET surface area, pore volume, pore size distribution, and pore diameter, were characterized from N(2) adsorption isotherms. The activated carbons obtained were essentially microporous and had BET surface area ranging from 303 to 2463 m(2) g(-1).
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