Tuning Water Networks via Ionic Liquid/Water Mixtures.

Water in nanoconfinement is ubiquitous in biological systems and membrane materials, with altered properties that significantly influence the surrounding system. In this work, we show how ionic liquid (IL)/water mixtures can be tuned to create water environments that resemble nanoconfined systems. We utilize molecular dynamics simulations employing force fields to extensively characterize the water structure within five different IL/water mixtures: [BMIM + ][BF 4 - ], [BMIM + ][PF 6 - ], [BMIM + ][OTf - ], [BMIM + ][NO 3 - ]and [BMIM + ][TFSI - ] ILs at varying water fraction.