Moss-like Hierarchical Architecture Self-Assembled by Ultrathin NaTiO Nanotubes: Synthesis, Electrical Conductivity, and Electrochemical Performance in Sodium-Ion Batteries.

Nanocrystalline layer-structured monoclinic NaTiO is currently under consideration for usage in solid state electrolyte applications or electrochemical devices, including sodium-ion batteries, fuel cells, and sensors. Herein, a facile one-pot hydrothermal synthetic procedure is developed to prepare self-assembled moss-like hierarchical porous structure constructed by ultrathin NaTiO nanotubes with an outer diameter of 6-9 nm, a wall thickness of 2-3 nm, and a length of several hundred nanometers. The phase and chemical transformations, optoelectronic, conductive, and electrochemical properties of as-prepared hierarchically-organized NaTiO nanotubes have been studied.

Enhancing Lithium and Sodium Storage Properties of TiO(B) Nanobelts by Doping with Nickel and Zinc.

Nickel- and zinc-doped TiO(B) nanobelts were synthesized using a hydrothermal technique. It was found that the incorporation of 5 at.% Ni into bronze TiO expanded the unit cell by 4%.