Effective separation of chromium species in technological solutions using amino-immobilized silica prior to their determination.

Amino-immobilized (poly(4,9-dioxadodecane-1,12-guanidine, polydiallyldimethylammonium, hexadimethrin bromide, polyhexamethylene guanidine) silicas were proposed for chromium speciation for the first time. Adsorbents surface was characterized by TGA-DSC, FT-IR, CHN, XRD and SEM analysis. Polyamines were strongly fixed on the silica surface and were not washed off with solutions of 3М HNO and 20 g L NaCl.