Background: Health literacy holds significant importance for medical professionals, as it is widely acknowledged as a key element in enhancing health promotion and overall well-being. The primary objective of this study is to explore Greek physicians' comprehension of health literacy, the significance they attribute to it, their strategies for addressing patients with low health literacy, and the potential barriers they face while striving to enhance a patient's health literacy. In this context, we examine the communication methods employed by physicians as an integral part of their approach to improving a patient's health literacy.
View Article and Find Full Text PDFThe development of superhydrophobic and/or superoleophobic materials has been attracting the attention of the scientific community due to their wide range of applications. In this work, waterborne nanocomposite coatings were developed to be deposited onto flexible polyethylene films in order to modify them into superhydrophobic and even superoleophobic. The coatings consisted of either a low surface energy mixture of silanes/siloxanes or a fluoropolymer in conjunction with the appropriate inorganic nanoparticles that provide the necessary roughness; the effects of nanoparticle type and content on the behaviour was investigated.
View Article and Find Full Text PDFPolymer science and technology is an active and continuously developing field of research and innovation in Greece [...
View Article and Find Full Text PDFThe dynamics of polymer chains in poly(ethylene oxide)/silica (PEO/SiO) nanoparticle nanohybrids have been investigated via a combined computational and experimental approach involving atomistic molecular dynamics simulations and dielectric relaxation spectroscopy (DRS) measurements. The complementarity of the approaches allows us to study systems with different polymer molecular weights, nanoparticle radii, and compositions across a broad range of temperatures. We study the effects of spatial confinement, which is induced by the nanoparticles, and chain adsorption on the polymer's structure and dynamics.
View Article and Find Full Text PDFThe development of a superhydrophobic and, even, water-repellent metal alloy surface is reported utilizing a simple, fast, and economical way that requires minimum demands on the necessary equipment and/or methods used. The procedure involves an initial irradiation of the metallic specimen using a femtosecond laser, which results in a randomly roughened surface, that is subsequently followed by placing the item in an environment under moderate vacuum (pressure 10 mbar) and/or under low-temperature heating (at temperatures below 120 °C). The effects of both temperature and low pressure on the surface properties (water contact angle and contact angle hysteresis) are investigated and surfaces with similar superhydrophobicity are obtained in both cases; however, a significant difference concerning their water-repellent ability is obtained.
View Article and Find Full Text PDFThanks to stem cells' capability to differentiate into multiple cell types, damaged human tissues and organs can be rapidly well-repaired. Therefore, their applicability in the emerging field of regenerative medicine can be further expanded, serving as a promising multifunctional tool for tissue engineering, treatments for various diseases, and other biomedical applications as well. However, the differentiation and survival of the stem cells into specific lineages is crucial to be exclusively controlled.
View Article and Find Full Text PDFNanocomposites of hyperbranched polymers with graphitic materials are investigated with respect to their structure and thermal properties as well as the dynamics of the polymer probing the effect of the different intercalated or exfoliated structure. Three generations of hyperbranched polyester polyols are mixed with graphite oxide (GO) and the favorable interactions between the polymers and the solid surfaces lead to intercalated structure. The thermal transitions of the confined chains are suppressed, whereas their dynamics show similarities and differences with the dynamics of the neat polymers.
View Article and Find Full Text PDFA series of well-defined (polyisoprene)(polystyrene), IS, single graft copolymers with similar total molecular weights but different compositions, , were blended with a low molecular weight polyisoprene homopolymer matrix at a constant concentration 2 wt%, and the micellar characteristics were studied by small-angle x-ray scattering. To investigate the effect of macromolecular architecture on the formation and characteristics of micelles, the results on the single graft copolymers were compared with those of the corresponding linear polystyrene--polyisoprene diblock copolymers, SI. The comparison reveals that the polystyrene core chains are more stretched in the case of graft copolymer micelles.
View Article and Find Full Text PDFWe investigated the tribological behavior of commercialized, fully synthetic engine oil upon the incorporation of reduced graphene oxide in seven different concentrations between 0.01 and 0.2 wt %.
View Article and Find Full Text PDFWe present a simulation study of amphiphilic mikto-arm star copolymers in a selective polymer host. By means of atomistic molecular dynamics simulations, we examine the structural and dynamical properties of mikto-arm stars with varying number, , of poly(ethylene oxide) (PEO) and polystyrene (PS) arms, (PEO) (PS) in a 33% wt blend with an oligomeric PEO host (o-PEO). As the number of arms increases, the stars resemble more spherical particles with less separated PEO and PS intramolecular domains.
View Article and Find Full Text PDFStud Health Technol Inform
September 2020
Smart devices, including the popular smart watches, often collect information on the heart beat rhythm and transmit it to a central server for storage or further processing. A factor introducing important limitations in the amount of data collected, transmitted and finally processed is the life of the mobile device or smart watch battery. Some devices choose to transmit the mean heart rate over relatively long periods of time, to save power.
View Article and Find Full Text PDFThe study of the coupling between structural and dynamical heterogeneities in nanostructured systems is essential for the design of hybrid materials with the desired properties. Here, we use atomistic molecular dynamics simulations to closely examine the dynamical heterogeneities in nanostructured single-molecule nanoparticles consisting of mikto-arm star copolymers with poly(ethylene oxide), PEO, and polystyrene, PS, arms. The particles exhibit an internally nanostructured morphology, resembling either "Janus-like" or "patchy-like" morphology when the functionality of the stars varies.
View Article and Find Full Text PDFQuaternized poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) brushes bearing quaternary ammonium groups of different alkyl chain lengths (ACLs) were prepared and assessed as biocidal coatings. For the synthesis of the antimicrobial brushes, first well-defined PDMAEMA chains were grown by surface-initiated atom transfer radical polymerization on glass and silicon substrates. Next, the tertiary amine groups of the polymer brushes were modified via a quaternization reaction, using alkyl halides, to obtain the cationic polymers.
View Article and Find Full Text PDFAnn Gastroenterol
October 2019
Background: Observational studies have shown an increased risk of upper gastrointestinal bleeding in users of selective serotonin receptor inhibitors (SSRIs). We retrospectively investigated the impact of SSRIs, alone or combined with aspirin (ASA) or nonsteroidal anti-inflammatory drugs (NSAIDs), on the incidence of post-endoscopic sphincterotomy (post-ES) bleeding.
Methods: A total of 3058 patients were included.
Eur Rev Med Pharmacol Sci
March 2019
Ann Gastroenterol
February 2019
Background: Endoscopic mucosal resection (EMR) is an established technique for treating large laterally spreading type (LST) lesions ≥20 mm. The aim of our study was to compare the use of argon plasma (APC) versus snare-tip coagulation on the recurrence rate of large LST lesions.
Methods: All patients with large LST lesions resected by EMR between January 2006 and December 2014 were enrolled.
Heterogeneous polymer-based nanoparticles comprise a very promising family of materials for a broad range of applications. Here, we present a detailed study of structural heterogeneities in nanostructured single-molecule nanoparticles in various environments by means of atomistic molecular dynamics simulations. The nanoparticles consist of mikto-arm star copolymers with two types of chemically incompatible arms, namely poly(ethylene oxide) (PEO) and polystyrene (PS), (PS) ,(PEO) , where n is the number of arms.
View Article and Find Full Text PDFThe structure and the dynamics of two bio-based polyester polyols are investigated in the bulk and close to surfaces in polymer/layered silicate nanocomposites. The morphology of the neat polymers as well as the structure of the nanohybrids are investigated with X-ray diffraction and their thermal properties are studied by differential scanning calorimetry. One of the investigated polyesters is amorphous, whereas the second one is a semicrystalline polymer with intriguing thermal behavior.
View Article and Find Full Text PDFWe have investigated the formation of lamellar crystals of poly(vinylidene fluoride) (PVDF) in the presence of oriented clay particles with different aspect ratios (ARs) and surface properties. Hot-melt screw extrusion of PVDF with 5 wt % of montmorillonite (AR ≈ 12) or fluoromica (AR ≈ 27) resulted in formation of phase-separated blends. Replacing the clays with their organoclay derivatives, organomontmorillonite or organofluoromica, resulted in the corresponding intercalated nanocomposites.
View Article and Find Full Text PDFWe present a detailed simulation study of the structural and dynamical behavior of star-shaped mikto-arm (polystyrene)8(poly(ethylene oxide))8, (PS)8(PEO)8, copolymers with eight arms of each type, versus that of a linear polystyrene-block-poly(ethylene oxide), PS-b-PEO, diblock, in a selective homopolymer host. Both copolymers are blended at the same weight fraction 33% with an oligomeric PEO host. We use atomistic molecular dynamics simulations to account for the molecular interactions present in the blends and to study quantitatively the dynamical and structural properties of these systems.
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