Effect of geochemical conditions on PFAS release from AFFF-impacted saturated soil columns.

Per- and polyfluoroalkyl substances (PFASs) are frequently found at high concentrations in the subsurface of aqueous film forming foam (AFFF)-impacted sites. Geochemical parameters affect the release of PFASs from source area soils into groundwater but have not been extensively studied for soils that have been historically impacted with AFFF. This study investigated the effects of pH and salt concentrations on release of anionic and zwitterionic PFASs from AFFF-impacted soils in flow-through saturated columns.

Biological and Chemical Transformation of the Six-Carbon Polyfluoroalkyl Substance -Dimethyl Ammonio Propyl Perfluorohexane Sulfonamide (AmPr-FHxSA).

Sites impacted by aqueous film-forming foam (AFFF) contain co-contaminants that can stimulate biotransformation of polyfluoroalkyl substances. Here, we compare how microbial enrichments from AFFF-impacted soil amended with diethyl glycol monobutyl ether (found in AFFF), aromatic hydrocarbons (present in co-released fuels), acetate, and methane (substrates used or formed during bioremediation) impact the aerobic biotransformation of an AFFF-derived six-carbon electrochemical fluorination (ECF) precursor -dimethyl ammonio propyl perfluorohexane sulfonamide (AmPr-FHxSA). We found that methane- and acetate-oxidizing cultures resulted in the highest yields of identifiable products (38 and 30%, respectively), including perfluorohexane sulfonamide (FHxSA) and perfluorohexane sulfonic acid (PFHxS).

Simulating Impacts of Biosparging on Release and Transformation of Poly- and Perfluorinated Alkyl Substances from Aqueous Film-Forming Foam-Impacted Soil.

Poly- and perfluorinated alkyl substances (PFASs) frequently co-occur with fuel-derived contaminants because of the use of aqueous film-forming foam (AFFF). Biosparging is a common remediation technology that injects oxygen into the saturated zone to encourage aerobic biodegradation, thereby altering aquifer redox conditions and potentially facilitating the biotransformation of polyfluorinated substances. Between 136 and 280 pore volumes of nitrogen-sparged or oxygen-sparged artificial groundwater amended with toluene were pumped through four saturated, AFFF-impacted soil columns to assess impacts on PFAS release and transformation.

Release of Per- and Polyfluoroalkyl Substances from Aqueous Film-Forming Foam Impacted Soils.

Per- and polyfluoroalkyl substances (PFASs) are highly mobile in the saturated subsurface, yet aqueous film-forming foam (AFFF)-impacted source zones appear to be long lasting PFAS reservoirs. This study examined the release of over one hundred anionic and zwitterionic PFASs from two AFFF-impacted surface soils under saturated conditions with packed soil columns. Perfluoroalkyl acids (PFAAs) were released more rapidly than their polyfluorinated precursors, while anionic PFASs that were present in partially uncharged states were released more slowly than PFASs that were present entirely as anions, as were zwitterionic PFASs with terminal cationic functional groups when compared with analogous zwitterions with only anionic terminal groups.

Diffusion of perfluoroalkyl acids through clay-rich soil.

Diffusion through a water saturated silty clay soil column was measured for six perfluoroalkyl acids (PFAAs), including perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS). An aqueous pore diffusion model, which incorporated linear adsorption parameters measured independently in batch tests and a tortuosity factor determined independently using a bromide tracer test, was used to describe the experimental diffusion data. The diffusion model substantially underpredicted PFAA diffusion through the soil column for the more strongly sorbing PFAAs (most notably PFOS).

Spatial Trends of Anionic, Zwitterionic, and Cationic PFASs at an AFFF-Impacted Site.

Soil and groundwater from an aqueous film-forming foam (AFFF)-impacted site were sampled at high resolution ( = 105 for soil, = 58 for groundwater) and analyzed for an extensive list of anionic, zwitterionic, and cationic poly- and perfluoroalkyl substances (PFASs). Spatial trends for perfluoroalkyl acids and many precursors enabled a better understanding of PFAS composition, transport, and transformation. All PFASs without analytical standards were semi-quantified.

Mass-Based, Field-Scale Demonstration of PFAS Retention within AFFF-Associated Source Areas.

Transport of poly- and perfluoroalkyl substances (PFAS) at aqueous film-forming foam (AFFF)-impacted sites is limited by various processes that can retain PFAS mass within the source area. This study used concentration data obtained via a high-resolution sampling and analytical protocol to estimate the PFAS mass distribution in source and downgradient areas of a former firefighter training area. The total PFAS mass present at the site was approximately 222 kg, with 106 kg as perfluoroalkyl acids (PFAAs) and 116 kg as polyfluorinated precursors.

Enhanced Extraction of AFFF-Associated PFASs from Source Zone Soils.

Poly- and perfluoroalkyl substances (PFASs) derived from aqueous film-forming foam (AFFF) are increasingly recognized as groundwater contaminants, though the composition and distribution of AFFF-derived PFASs associated with soils and subsurface sediments remain largely unknown. This is particularly true for zwitterionic and cationic PFASs, which may be incompletely extracted from subsurface solids by analytical methods developed for anionic PFASs. Therefore, a method involving sequential basic and acidic methanol extractions was developed and evaluated for recovery of anionic, cationic, and zwitterionic PFASs from field-collected, AFFF-impacted soils.

Removal of per- and polyfluoroalkyl substances using super-fine powder activated carbon and ceramic membrane filtration.

Contamination of drinking water sources with per- and polyfluoroalkyl substances (PFASs) is a major challenge for environmental engineers. While granular activated carbon (GAC) is an effective adsorbent-based treatment technology for long-chained PFASs, GAC is less effective for removal of short-chained compounds, necessitating a more complete treatment strategy. Super-fine powder activated carbon (SPAC; particle diameter <1 um) is potentially a superior adsorbent to GAC due to high specific surface area and faster adsorption kinetics.