Critical evaluation of the NIST retention index database reliability with specific examples.

The NIST gas chromatographic retention index database is widely used in gas chromatography-mass spectrometry analysis. For many compounds, the NIST database contains many entries that are presumably obtained independently of each other. We showed with specific examples that there are cases in the NIST database where several entries exist for the same compound, and all of them are equally erroneous (an error of more than 100 units).

Validation of the identification reliability of known and assumed UDMH transformation products using gas chromatographic retention indices and machine learning.

Thirty two commercially available standards were used to determine chromatographic retention indices for three different stationary phases (non-polar, polar and mid-polar) commonly used in gas chromatography. The selected compounds were nitrogen-containing heterocycles and amides, which are referred to in the literature as unsymmetrical dimethylhydrazine (UDMH) transformation products or its assumed transformation products. UDMH is a highly toxic compound widely used in the space industry.

Unsymmetrical dimethylhydrazine transformation products: A review.

Unsymmetrical dimethylhydrazine (UDMH) is a widely used rocket propellant, which oxidizes to different compounds. The determination of UDMH transformation products in the environment is of great importance since many of them are highly toxic. Along with well-known transformation products, researchers report new compounds, and establishing their structures is difficult and may be unreliable, and data on their properties, such as toxicity, are often not available.

The mysterious mass death of marine organisms on the Kamchatka Peninsula: A consequence of a technogenic impact on the environment or a natural phenomenon?

The increased incidence of environmental disasters in recent years is a matter of serious concern. The reasons for the disaster on the Kamchatka Peninsula (Russia), which occurred in September 2020 and caused the mass death of marine organisms, have not yet been established. This is the first study of the environmental disaster on Kamchatka and should shed light on the possible impact of two main man-made factors associated with an oil spill and a rocket fuel spill.

Isomeric derivatives of triazoles as new toxic decomposition products of 1,1-dimethylhydrazine.

Unsymmetrical dimethylhydrazine (UDMH) is a rocket propellant for carrier rockets and missiles. UDMH is environmentally hostile compound, which easily forms a variety of toxic products of oxidative transformation. The liquidation of unused UDMH from retired launch sites is performed by the complete burning of UDMH-containing wastes.