[Optimizing Savitzky-Golay Parameters and Its Smoothing Pretreatment for FTIR Gas Spectra].

In the smoothing pretreatment for the quantitative analysis of hydrocarbon mixed gases by Fourier transform infrared analysis (FTIR), the Savitzky- Golay filter is usually used as one of the smoothing preprocessing methods in the Fourier transform infrared spectrum data smoothing pretreatment. However, the parameters of the Savitzky-Golay filter such as the polynomial order and frame size are not easy to decide. There is no one unified choice basis.

[Using 2-DCOS to identify the molecular spectrum peaks for the isomer in the multi-component mixture gases Fourier transform infrared analysis].

The generalized two-dimensional correlation spectroscopy and Fourier transform infrared were used to identify hydrocarbon isomers in the mixed gases for absorption spectra resolution enhancement. The Fourier transform infrared spectrum of n-butane and iso-butane and the two-dimensional correlation infrared spectrum of concentration perturbation were used for analysis as an example. The all band and the main absorption peak wavelengths of Fourier transform infrared spectrum for single component gas showed that the spectra are similar, and if they were mixed together, absorption peaks overlap and peak is difficult to identify.

[The spectral characteristic wavelength selection and parameter optimization based on Tikhonov regularization].

In the multicomponent mixture hydrocarbon gases Fourier transform infrared (FTIR) quantitative analysis, especially for light alkane gases, it is not easy to establish the quantitative analysis model because their IR spectra absorption peaks are seriously overlapped. Aiming at this problem, the Tikhonov regularization algorithm was used to select the characteristic wavelengths for seven kinds of light alkane mixture gases FTIR which are composed with methane, ethane, propane, iso-butane, n-butane, iso-pentane and n-pentane. And then the wavelength selection was used to establish the quantitative analysis model.