Here, we present the electrochemical determination of ammonium in water samples, emphasizing the importance of accurate and precise assessment of its concentration. The modified electrode used in this study was fabricated through the anodic polymerization of 1-aminoanthraquinone (1-AAQ) and deposition of silver particles into a carbon paste electrode. The fabrication process involved cyclic voltammetry in a 0.
View Article and Find Full Text PDFJ Environ Manage
July 2024
The nature of nano molecules as a self-assembled nanocomposite surface depends on the nanoparticles of sodium butyrate, cellulose, and pycnogenol; the synthesis is achieved via precipitation and grinding methods. The excellent functionalized surface of nanocomposite (NCP) enables the loading of the selected drugs, where the efficiency of the NCP surface arrived at 92.2 %.
View Article and Find Full Text PDFA selective and reliable modified glassy carbon sensor, based on a 1.0% Cd zeolitic imidazole framework-67 modified glassy carbon sensor (GCS), has been developed for ultrasensitive detection of dimethyl methyl phosphonate (DMMP) in human biological fluid. The synthesis of porous nanoparticles of Cd zeolitic imidazole framework-67 (Cd ZIF-67) was carried out via the hydrothermal method.
View Article and Find Full Text PDFIn this study, silver nanoparticles (AgNPs)-based electrochemical sensor has been reported for assessing bromocresol green (BG) in river water. Firstly, AgNPs were greenly produced using the aqueous extract of leaves. Then, the AgNP-modified glassy carbon (GC) electrode was prepared using the sticking method.
View Article and Find Full Text PDFSelenite (Se), a significant source of water pollution above the permissible limits, is considered a valuable metal by environmentalists. In this study, we described a novel electrochemical sensor that utilized a carbon paste electrode (CPE) that was modified using multiwall carbon nanotubes (MWCNTs) and poly(1-aminoanthraquinone) (p-AAQ) for finding Se in water samples. Electrochemical quantification of Se depends on the formation of a selective complex (piaselenol) with p-AAQ.
View Article and Find Full Text PDFIpriflavone is a nonhormonal isoflavone derivative currently used as a bone-building agent for prevention and treatment of postmenopausal osteoporosis. Ipriflavone was reduced at the hanging mercury drop electrode in buffers of pH 2-11 via the consumption of 2 electrons corresponding to the reduction of the C=O double bond in the C 4 position of the analyte molecule. A fully validated square-wave adsorptive cathodic stripping (SW-AdCS) voltammetric method was described for the trace quantification of bulk ipriflavone, A linear response, with concentrations of bulk ipriflavone over the range 5 x 10(-9)-4 x 10(-7) M with a limit of detection of 1.
View Article and Find Full Text PDFAn easy, rapid and selective adsorptive stripping voltammetry (AdSV) method for the determination of vincamine in its formulation and human serum was developed and validated. It was based on the oxidation of the drug onto a Nujol-based carbon paste electrode. The stripping step was carried out by using a square-wave (SW) potential-time voltammetric excitation signal.
View Article and Find Full Text PDFThe electrochemical oxidative behavior of terbutaline at the glassy carbon electrode was studied in a series of the Britton-Robinson buffer of pH 2--11. Cyclic and square-wave voltammograms of terbutaline at the pH values =9 exhibited a single irreversible anodic peak. A fully validated, simple, sensitive and precise square-wave adsorptive anodic stripping voltammetric procedure was described for the determination of terbutaline in bulk form, tablets and human serum.
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