Angew Chem Int Ed Engl
January 2025
Li-TFSI/t-BP is the most widely utilized p-dopant for hole-transporting materials (HTMs) in state-of-the-art perovskite solar cells (PSCs). However, its nonuniformity of doping, along with the hygroscopicity and migration of dopants, results in the devices exhibiting limited stability and performance. This study reports on the utilization of a spherical anion derived from the p-dopant, regulated by its radius and shape, as an alternative to the linear TFSI anion.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
November 2024
Hole-transporting material (HTMs) are crucial for obtaining the stability and high efficiency of perovskite solar cells (PSCs). However, the current state-of-the-art n-i-p PSCs relied on the use of 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD) exhibit inferior intrinsic and ambient stability due to the p-dopant and hydrophilic Li-TFSI additive. In this study, a new spiro-type HTM with a critical quasi-planar core (Z-W-03) is developed to improve both the thermal and ambient stability of PSCs.
View Article and Find Full Text PDFObjectives: This study aimed to determine the normal vasculature indices of the endometrium and to correlate them with those in various physiological states.
Methods: Women undergoing ultrasound at the Feto-Maternal Center, Qatar in 2020-2021 as part of their gynecologic evaluation were enrolled into the study. They were divided into those with normal menses and no additional pathology, those following spontaneous miscarriage, postpartum and menopausal.
Ultrasound technique is one of the green technologies that is being utilized widely for varying food processes. Our aim in this study was to carry out ultrasonication, pasteurization and chemical preservation (Potassium metabisulfite) techniques on a carrot-orange juice blend. Additionally, the effect of these treatments on the storage period of about 21 days was also determined.
View Article and Find Full Text PDFOlive family (Oleaceae) contains several species among which L. is mostly used for production of olive oils. Various parts of olive tree are rich source of diverse bioactive compounds such as Apigenin, elenolic acid, Hydroxytyrosol, Ligstroside, Oleoside, Oleuropein, Oleuropein aglycone, Tyrosol, etc.
View Article and Find Full Text PDFGlobally, the prevalence of vit-A deficiency disorders i.e., xerophthalmia and nyctalopia is increasing especially in teenagers due to lifestyle shifts and undernutrition.
View Article and Find Full Text PDFAdvances in multifunctional materials and technologies have allowed contact lenses to serve as wearable devices for continuous monitoring of physiological parameters and delivering drugs for ocular diseases. Since the tear fluids comprise a library of biomarkers, direct measurement of different parameters such as concentration of glucose, urea, proteins, nitrite, and chloride ions, intraocular pressure (IOP), corneal temperature, and pH can be carried out non-invasively using contact lens sensors. Microfluidic contact lens sensor based colorimetric sensing and liquid control mechanisms enable the wearers to perform self-examinations at home using smartphones.
View Article and Find Full Text PDFThe application of triphenylene-based discotic liquid crystal derivatives as physical gelators is investigated. In particular, we focus on 2,3,6,7,10,11-hexakis-pentyloxytriphenylene (HAT5) and the longer alkyl chain homologue (HAT6). The driving mechanisms behind and parameter space of non-covalent physical gel formation is studied.
View Article and Find Full Text PDFLiquid crystals are of technological interest as they allow for optical effects which can be electrically controlled. In this paper we present an electro-optical device consisting of nematic liquid crystals addressed by an electrode structure consisting of thin films of polymer wrapped single walled carbon nanotubes (nanohybrids). Thin films of nanohybrids display excellent optical transmission and electrical conduction properties.
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