The specific energies and energy densities of lithium-sulfur (Li-S) batteries are influenced by various cell parameters, including the sulfur loading, the sulfur weight percentage in the cathode, and the electrolyte/sulfur ratio. An InS/BiS@rGO heterostructure was obtained by growing indium sulfide nanoparticles on the surface of bismuth sulfide nanoflowers in a graphene oxide (GO) solution via a one-step solvothermal approach. This structure was introduced as a modified separator/dual-layer sulfur cathode for Li-S batteries.
View Article and Find Full Text PDFBecause of its high theoretical capacity and energy density, the lithium-sulfur (Li-S) battery is a desirable next-generation energy storage technology. However, the shuttle effect of lithium polysulfide and the slow sulfur reaction kinetics remain significant barriers to Li-S battery application. In this work, tantalum trisulfide (TaS) and selective manganese-doped tantalum trisulfide (Mn-TaS) nanocomposites on reduced graphene oxide surface were developed via a one-step hydrothermal method for the first time and introduced as a novel multifunctional mediator in the Li-S battery.
View Article and Find Full Text PDFThe poor conductivity of sulfur, the lithium polysulfide's shuttle effect, and the lithium dendrite problem still impede the practical application of lithium-sulfur (Li-S) batteries. In this work, the ultrathin nickel-doped tungsten sulfide anchored on reduced graphene oxide (Ni-WS@rGO) is developed as a new modified separator in the Li-S battery. The surface engineering of Ni-WS@rGO could enhance the cell conductivity and afford abundant chemical anchoring sites for lithium polysulfides (LiPSs) adsorption, which is convinced by the high adsorption energy and the elongate SS bond given using density-functional theory (DFT) calculation.
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