Half-sandwich complexes of osmium containing guanidine-derived ligands.

Pyridinyl- and phosphano-guanidino complexes of formula [(η6-p-cymene)OsCl(H2L)][SbF6] (cymene = MeC6H4iPr; H2L = N,N'-bis(p-Tolyl)-N''-(2-pyridinylmethyl)guanidine, H2L1 (1) and N,N'-bis(p-Tolyl)-N''-(2-diphenylphosphanoethyl)guanidine, H2L2 (2)) have been prepared from the dimer [{(η6-p-cymene)OsCl}2(μ-Cl)2] and H2L in the presence of NaSbF6. Treatment of complex 2 with HCl renders the phosphano-guanidinium complex [(η6-p-cymene)OsCl2(H3L2)][SbF6] (3). Compounds 1 and 2 react with AgSbF6 rendering the cationic aqua complexes [(η6-p-cymene)Os(H2L)(OH2)][SbF6]2 (H2L = H2L1 (4), H2L2 (5)).