Control over Charge Density by Tuning the Polyelectrolyte Type and Monomer Ratio in Saloplastic-Based Ion-Exchange Membranes.

Membranes based on polyelectrolyte complexes (PECs) can now be prepared through several sustainable, organic solvent-free approaches. A recently developed approach allows PECs made by stoichiometric mixing of polyelectrolytes to be hot-pressed into dense saloplastics, which then function as ion-exchange membranes. An important advantage of PECs is that tuning their properties can provide significant control over the properties of the fabricated materials, and thus over their separation properties.

Hot-pressed polyelectrolyte complexes as novel alkaline stable monovalent-ion selective anion exchange membranes.

Polymeric ion-exchange membranes have come a long way since their invention, benefiting a wide range of processes, ranging from desalination to fuel cells. However, challenges such as alkaline stability, monovalent ion selectivity, cost-effectivity, and process sustainability largely persist. This work showcases alkaline stable anion-exchange membranes made by hot-pressing of a polyelectrolyte complex of poly(styrenesulfonate) (PSS) and poly(diallyldimethylammonium) (PDADMA).