Photoaligning Polymeric Command Surfaces: Bind, or Mix?

We compare photoaligning properties of polymer layers fabricated from the same constituents: polymethyl-methacrylate (PMMA) and azo-dye Disperse Red 1 (DR1), either chemically attached to the PMMA main-chain, or physically mixed with it. Photoaligning properties depend on the preparation method drastically. Photoalignment was found to be far more efficient when PMMA is functionalized with DR1 compared to the case of physically mixing the constituents.

Polymer-Nematic Liquid Crystal Interface: On the Role of the Liquid Crystalline Molecular Structure and the Phase Sequence in Photoalignment.

We provide experimental evidence for the influence of the molecular structure of the nematic liquid crystal (NLC) on the photoalignment process in three dimensions at the interface with a polymer layer. In particular, the experimental findings are explained through the presence (or absence) of the π-π aromatic interactions between the NLC and the polymer. The influence of the nematic-to-smectic A phase transition on the photocontrol is also addressed.