Publications by authors named "Amaia Butron"

A new phosphate-containing bio-polyester based on glycerol and citric acid was synthesized and evaluated as fire-retardant (FR) in wooden particleboards. Phosphorus pentoxide was used to first introduce phosphate esters in the glycerol followed by esterification with citric acid to produce the bio-polyester. The phosphorylated products were characterized by ATR-FTIR, H-NMR and TGA-FTIR.

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Bamboo constitutes a family of plants that are very promising and interesting as renewable materials for both large and small structure construction. To be used as an alternative to traditional materials; the understanding of its morphology and mechanical behavior is of crucial importance. As the distribution of fibers and vascular bundles differs for each type of bamboo; several bamboo types have been characterized: Phyllostachys aurea (PA), Arundinaria amabilis (AA) and (DS).

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Poly(ethylene brassylate), a novel inexpensive biodegradable polyester, has been reinforced with cellulose nanocrystals (CNCs) with the aim of improving its thermal stability and mechanical properties. The composites have been characterized through calorimetry, tensile tests, thermogravimetry and electron microscopy. The addition of small amounts of CNCs improves both the stiffness and the ductility of the composites, suggesting the existence of some compatibilizing effect.

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Article Synopsis
  • The conformational behavior of chloramphenicol (CHL) has been studied across solid, liquid, and vapor phases using FTIR spectroscopy and quantum mechanics (QM) methods.
  • In the crystalline phase, the results support a conformer with an intramolecular OH⋯O hydrogen bond, rejecting earlier proposed conformers.
  • In liquid phase studies, a reversal of the hydrogen bond donor occurs, and new intramolecular CCl⋯π halogen bonds are formed, leading to the identification of distinct stable conformers that can be detected via FTIR due to their sensitivity to conformational changes.
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