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View Article and Find Full Text PDFWe show that the dissociation probability of O2 on the reconstructed, Au111-herringbone surface is dramatically increased by the presence of some atomic oxygen on the surface. Specifically, at 400 K the dissociation probability of O2 on oxygen precovered Au111 is on the order of 10(-3), whereas there is no measurable dissociation on clean Au111, establishing an upper bound for the dissociation probability of 10(-6). Atomic oxygen was deposited on the clean reconstructed Au111-herringbone surface using electron bombardment of condensed NO2 at 100 K.
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