Influence of Oxygen-Containing Functional Groups on the Environmental Properties, Transformations, and Toxicity of Carbon Nanotubes.

Carbon nanotubes (CNTs) have unique physical and chemical properties that drive their use in a variety of commercial and industrial applications. CNTs are commonly oxidized prior to their use to enhance dispersion in polar solvents by deliberately grafting oxygen-containing functional groups onto CNT surfaces. In addition, CNT surface oxides can be unintentionally formed or modified after CNTs are released into the environment through exposure to reactive oxygen species and/or ultraviolet irradiation.

UV-Vis quantification of hydroxyl radical concentration and dose using principal component analysis.

Hydroxyl radicals (∙OH) are powerful oxidizing species formed naturally in the environment or artificially produced to destroy contaminants in water treatment facilities. Their short lifetime and high reactivity, however, present a significant challenge to quantifying their concentration in solution. Herein, we developed a novel method to accurately measure the steady-state ∙OH concentration and total ∙OH dose produced during the UV photolysis of hydrogen peroxide (HO) by monitoring the loss of salicylic acid (SA).

Photochemical Transformations of Carbon Dots in Aqueous Environments.

The unique physicochemical and luminescent properties of carbon dots (CDs) have motivated research efforts toward their incorporation into commercial products. Increased use of CDs will inevitably lead to their release into the environment where their fate and persistence will be influenced by photochemical transformations, the nature of which is poorly understood. This knowledge gap motivated the present investigation of the effects of direct and indirect photolysis on citric and malic acid-based CDs.