Publications by Alyson MacKay

Publications by authors named "Alyson MacKay"

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Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes.

Hardeep Singh Alyson MacKay Nooshin Sheibany Fei Chen Maëlle Mosser

Chem Commun (Camb)

October 2021

Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design an intramolecular hydrogen bond. Six metal complexes with an intact NHOH group were synthesized and crystallographically characterized.

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