Political change as group-based control: Threat to personal control reduces the support for traditional political parties.

People desire agentic representations of their personal and collective selves, such as their own nation. When national agency is put into question, this should increase their inclination to restore it, particularly when they simultaneously lack perceptions of personal control. In this article, we test this hypothesis of group-based control in the context of political elections occurring during socio-economic crises.

Walk This Way: Ingroup Norms Determine Voting Intentions for Those Who Lack Sociopolitical Control.

Even though taking part in elections is one of the most direct tools to influence the sociopolitical system, many people choose not to vote. Research shows that this problem is especially prevalent among those citizens who do not believe they have control over social and political issues, but the question remains as to what could encourage their voting behavior. We predicted that individuals who experience low levels of control can be more susceptible to ingroup norms regarding participation in political elections than those with a high sense of sociopolitical control (SPC).

Pummerer Synthesis of Chromanes Reveals a Competition between Cyclization and Reductive Chlorination.

The competition between an unprecedented reductive chlorination and the Pummerer reaction was studied and applied to the synthesis of benzofused oxygen heterocycles including 3-aminochromanes and in the intramolecular chlorination of activated aromatic rings. The use of (COCl) as a Pummerer activator showed substantial activity, producing α-chlorinated sulfides that can undergo Pummerer-Friedel-Crafts cyclization. If the aromatic ring has electron-donating groups in position three, then the reaction follows a different pathway, yielding the reductive chlorination products, where the chlorine atom comes from a sulfonium salt.