Advanced Hybrid System for Ammonium Valorization as Liquid Fertilizer from Treated Urban Wastewaters: Validation of Natural Zeolites Pretreatment and Liquid-Liquid Membrane Contactors at Pilot Plant Scale.

This study evaluates a hybrid system combining zeolites as a sorption stage and a hollow fiber membrane contactor (HFMC) for ammonia (NH) recovery from treated urban wastewater. Ion exchange with zeolites was selected as an advanced pretreatment and concentration step before the HFMC. The system was tested with wastewater treatment plant (WWTP) effluent (mainstream, 50 mg N-NH/L) and anaerobic digestion centrates (sidestream, 600-800 mg N-NH/L) from another WWTP.

Life-cycle assessment and techno-economic evaluation of the value chain in nutrient recovery from wastewater treatment plants for agricultural application.

The recovery of nitrogen and phosphorus is important to promote circular economy in wastewater treatment plants (WWTPs). In this study, the life cycle assessment (LCA) and techno-economic assessment (TEA) of a novel pilot-scale plant aimed at recovering ammonium nitrate and struvite for subsequent application in agriculture was conducted. The nutrient recovery scheme was implemented in the sludge line of the WWTP and included (i) struvite crystallisation and (ii) ion-exchange process combined with gas permeable membrane contactor.

Nitrogen flow analysis in Spain: Perspectives to increase sustainability.

Nitrogen (N) is a macronutrient that, together with P and K, is vital for improving agricultural yields, but its excessive use in crop fertilisation and presence in treated wastewater and sludge are generating emissions both into the atmosphere and into natural water bodies, which leads to eutrophication events. The Haber-Bosch process is energy-intensive and it is the main chemical route to produce reactive nitrogen for the production of fertilisers. Furthermore, there is a strong dependence on imports of reactive nitrogen in Spain and Europe.