The current work describes a facile synthesis of spinel-type ZnCoO along with an additional phase, CoO, by simply maintaining a non-stoichiometric ratio of Zn and Co precursors. Pure ZnCoO and CoO were also synthesized using the same method to compare results. The obtained morphologies of samples show that small-sized nanoparticles are interconnected and form a porous nanosheet-like structure.
View Article and Find Full Text PDFHerein, a mesoporous MnCoO/CoO nanocomposite was fabricated using a polyvinylpyrrolidone (PVP)-assisted hydrothermal synthesis method by maintaining only the non-stoichiometric ratio of Mn and Co (2 : 6), leading to an extra phase of CoO coupled with MnCoO. Microstructural analysis showed that the obtained sample has a uniform nanowire-like morphology composed of interconnected nanoparticles. The stoichiometric ratio (2 : 4) was maintained to synthesize pure MnCoO for comparative analysis.
View Article and Find Full Text PDFRecently, aqueous zinc ion batteries (AZIBs) have attracted significant attention owing to their high safety, low cost, and abundant raw materials. However, finding an affordable and stable cathode, which can reversibly store a substantial amount of Zn ions without damaging the original crystal structure, is still a major challenge for the practical application of ZIBs. It has already been demonstrated that δ-MnO is a promising cathode for AZIBs owing to its layered structure and superior electrochemical performance; however, the reported results are still unsatisfactory (especially cyclability).
View Article and Find Full Text PDFThe discontinuous interfacial contact of solid-state polymer metal batteries is due to the stress changes in the electrode structure during cycling, resulting in poor ion transport. Herein, a rigid-flexible coupled interface stress modulation strategy is developed to solve the above issues, which is to design a rigid cathode with enhanced solid-solution behavior to guide the uniform distribution of ions and electric field. Meanwhile, the polymer components are optimized to build an organic-inorganic blended flexible interfacial film to relieve the change of interfacial stress and ensure rapid ion transmission.
View Article and Find Full Text PDFIn this study, V doped sodium titanate nanorods were successfully synthesized by a sol-gel method with different optimized vanadium concentrations. Before testing as a promising anode material for sodium ion battery (SIB) application, the samples were systematically characterized. It was clearly observed that V doping significantly affects the phase formation of sodium titanate samples and leads to the alteration of the major phase of NaTiO to a single NaTiO phase with increasing doping concentrations.
View Article and Find Full Text PDFIntroduction: Posterior tibial plateau fractures (PTPF) are difficult to manage because of options of multiple approaches, paucity of implants, and lack of ideal construct for fixation. We investigated the benefits of using posterior approach and buttress plate for fixation of the posterior tibial condylar fractures in terms of the fracture healing rate, clinico-radiological, perioperative morbidity, and patient-related outcomes and compared them in those who achieved acceptable reduction without posterior stabilization.
Patients And Methods: Seventy two patients with posterior tibial plateau fractures were prospectively followed after random allocation into two Groups A and B.
A simple and low cost urea-assisted auto-combustion route was investigated for the synthesis of carbon coated CoO nanocomposite. CHN analysis determined the carbon content in CoO/C nanocomposite to be very low as 0.27 wt%.
View Article and Find Full Text PDF