Benefits and Cautions in Data Assimilation Strategies: An Example of Modeling Groundwater Recharge.

Assimilating recent observations improves model outcomes for real-time assessments of groundwater processes. This is demonstrated in estimating time-varying recharge to a shallow fractured-rock aquifer in response to precipitation. Results from estimating the time-varying water-table altitude (h) and recharge, and their error covariances, are compared for forecasting, filtering, and fixed-lag smoothing (FLS), which are implemented using the Kalman Filter as applied to a data-driven, mechanistic model of recharge.

Application of Recursive Estimation to Heat Tracing for Groundwater/Surface-Water Exchange.

We present and demonstrate a recursive-estimation framework to infer groundwater/surface-water exchange based on temperature time series collected at different vertical depths below the sediment/water interface. We formulate the heat-transport problem as a state-space model (SSM), in which the spatial derivatives in the convection/conduction equation are approximated using finite differences. The SSM is calibrated to estimate time-varying specific discharge using the Extended Kalman Filter (EKF) and Extended Rauch-Tung-Striebel Smoother (ERTSS).

Incorporating Snowmelt into Daily Estimates of Recharge Using a State-Space Model of Infiltration.

A state-space model (SSM) of infiltration estimates daily groundwater recharge using time-series of groundwater-level altitude and meteorological inputs (liquid precipitation, snowmelt, and evapotranspiration). The model includes diffuse and preferential flow through the unsaturated zone, where preferential flow is a function of liquid precipitation and snowmelt rates and a threshold rate, above which there is direct recharge to the water table. Model parameters are estimated over seasonal periods and the SSM is coupled with the Kalman Filter (KF) to assimilate recent observations (hydraulic head) and meteorological inputs into recharge estimates.

Contributing Areas to Domestic Wells in Dipping Sedimentary Rocks under Extreme Recharge Events.

We use particle tracking to determine contributing areas (CAs) to wells for transient flow models that simulate cyclic domestic pumping and extreme recharge events in a small synthetic watershed underlain by dipping sedimentary rocks. The CAs consist of strike-oriented bands at locations where the water table intersects high-hydraulic conductivity beds, and from which groundwater flows to the pumping well. Factors that affect the size and location of the CAs include topographic flow directions, rock dip direction, cross-bed fracture density, and position of the well relative to streams.

The complex spatial distribution of trichloroethene and the probability of NAPL occurrence in the rock matrix of a mudstone aquifer.

Methanol extractions for chloroethene analyses are conducted on rock samples from seven closely spaced coreholes in a mudstone aquifer that was subject to releases of the nonaqueous phase liquid (NAPL) form of trichloroethene (TCE) between the 1950's and 1990's. Although TCE concentration in the rock matrix over the length of coreholes is dictated by proximity to subhorizontal bedding plane fractures, elevated TCE concentrations in the rock matrix are not continuous along the most permeable bedding plane fractures. A complex configuration of subvertical and subhorizontal fractures appears to be responsible for the TCE distribution from prior TCE releases at land surface.

Variability of organic carbon content and the retention and release of trichloroethene in the rock matrix of a mudstone aquifer.

Contaminants diffusing from fractures into the immobile porosity of the rock matrix are subject to prolonged residence times. Organic contaminants can adsorb onto organic carbonaceous materials in the matrix extending contaminant retention. An investigation of spatial variability of the fraction of organic carbon (f) is conducted on samples of rock core from seven closely spaced boreholes in a mudstone aquifer contaminated with trichloroethene (TCE).

Bioremediation in Fractured Rock: 1. Modeling to Inform Design, Monitoring, and Expectations.

Field characterization of a trichloroethene (TCE) source area in fractured mudstones produced a detailed understanding of the geology, contaminant distribution in fractures and the rock matrix, and hydraulic and transport properties. Groundwater flow and chemical transport modeling that synthesized the field characterization information proved critical for designing bioremediation of the source area. The planned bioremediation involved injecting emulsified vegetable oil and bacteria to enhance the naturally occurring biodegradation of TCE.

Bioremediation in Fractured Rock: 2. Mobilization of Chloroethene Compounds from the Rock Matrix.

A mass balance is formulated to evaluate the mobilization of chlorinated ethene compounds (CE) from the rock matrix of a fractured mudstone aquifer under pre- and postbioremediation conditions. The analysis relies on a sparse number of monitoring locations and is constrained by a detailed description of the groundwater flow regime. Groundwater flow modeling developed under the site characterization identified groundwater fluxes to formulate the CE mass balance in the rock volume exposed to the injected remediation amendments.

Porosity and pore size distribution in a sedimentary rock: Implications for the distribution of chlorinated solvents.

Characterizing properties of the rock matrix that control retention and release of chlorinated solvents is essential in evaluating the extent of contamination and the application of remediation technologies in fractured rock. Core samples from seven closely spaced boreholes in a mudstone subject to trichloroethene (TCE) contamination were analyzed using Mercury Intrusion Porosimetry to investigate porosity and pore size distribution as a function of mudstone characteristics, and depth and lateral extent in the aquifer; organic carbon content was also evaluated to identify the potential for adsorption. Porosity and retardation factor varied over two orders of magnitude, with the largest porosities and largest retardation factors associated with carbon-rich mudstone layers.

Imaging Pathways in Fractured Rock Using Three-Dimensional Electrical Resistivity Tomography.

Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes.

Integration of stable carbon isotope, microbial community, dissolved hydrogen gas, and ²HH₂O tracer data to assess bioaugmentation for chlorinated ethene degradation in fractured rocks.

An in situ bioaugmentation (BA) experiment was conducted to understand processes controlling microbial dechlorination of trichloroethene (TCE) in groundwater at the Naval Air Warfare Center (NAWC), West Trenton, NJ. In the BA experiment, an electron donor (emulsified vegetable oil and sodium lactate) and a chloro-respiring microbial consortium were injected into a well in fractured mudstone of Triassic age. Water enriched in ²H was also injected as a tracer of the BA solution, to monitor advective transport processes.

Radon (222Rn) in ground water of fractured rocks: a diffusion/ion exchange model.

Ground waters from fractured igneous and high-grade sialic metamorphic rocks frequently have elevated activity of dissolved radon (222Rn). A chemically based model is proposed whereby radium (226Ra) from the decay of uranium (238U) diffuses through the primary porosity of the rock to the water-transmitting fracture where it is sorbed on weathering products. Sorption of 226Ra on the fracture surface maintains an activity gradient in the rock matrix, ensuring a continuous supply of 226Ra to fracture surfaces.

Effect of cell physicochemical characteristics and motility on bacterial transport in groundwater.

The influence of physicochemical characteristics and motility on bacterial transport in groundwater were examined in flow-through columns. Four strains of bacteria isolated from a crystalline rock groundwater system were investigated, with carboxylate-modified and amidine-modified latex microspheres and bromide as reference tracers. The bacterial isolates included a gram-positive rod (ML1), a gram-negative motile rod (ML2), a nonmotile mutant of ML2 (ML2m), and a gram-positive coccoid (ML3).

Bacterial transport experiments in fractured crystalline bedrock.

The efficiency of contaminant biodegradation in ground water depends, in part, on the transport properties of the degrading bacteria. Few data exist concerning the transport of bacteria in saturated bedrock, particularly at the field scale. Bacteria and microsphere tracer experiments were conducted in a fractured crystalline bedrock under forced-gradient conditions over a distance of 36 m.