The pure rotational spectrum of ruthenium monocarbide, RuC, and relativistic ab initio predictions.

The J = 1 ← J = 0 and J = 2 ← J = 1 rotational transitions of ruthenium monocarbide, RuC, have been recorded using the separated field pump/probe microwave optical double resonance technique and analyzed to determine the fine and hyperfine parameters for the X(1)Σ(+) state. The (101)Ru(I = 5/2) electric quadrupole parameter, eq0Q, and nuclear spin-rotation interaction parameter, C(I)(eff), were determined to be 433.19(8) MHz and -0.

Hyperfine interactions in the A3Φ4 and X3Φ4 states of iridium monofluoride, IrF.

Laser induced-fluorescence spectra of the 1-0 band of the A(3)Φ(4)-X(3)Φ(4) transition of iridium monofluoride, IrF, have been obtained at near natural linewidth resolution using supersonic molecular beam techniques. The spectra show a complex, clearly resolved hyperfine structure which has significant contributions from the magnetic and quadrupole hyperfine terms in (193)Ir and (191)Ir, both with I = 3/2, and the fluorine magnetic hyperfine term (I = 1∕2). The spectra of both (193)IrF and (191)IrF isotopologues have been assigned and analyzed.

A molecular beam optical Stark study of the [15.8] and [16.0] 2Pi1/2-X 4Sigma- (0,0) band systems of rhodium monoxide, RhO.

The SR11(0) and SR11(1) branch features of the [15.8] and [16.0]2Pi1/2-X 4Sigma- (0,0) subband systems of rhodium monoxide, RhO, have been studied at near the natural linewidth limit of resolution by optical Stark spectroscopy using laser induced fluorescence detection.

High resolution laser induced fluorescence spectroscopy of the [18.8] 3Phi(i)-X 3Phi(i) (0,0) band of cobalt monofluoride.

The fine and hyperfine interaction parameters in the [18.8] (3)Phi (upsilon=0) and X (3)Phi (upsilon=0) states of cobalt monofluoride, CoF, have been determined from an analysis of high-resolution laser induced fluorescence spectra of the [18.8] (3)Phi(3)-X (3)Phi(3) and [18.

A laser spectroscopic study of the X2pi(g), A2pi(u), and B2sigma+ states of BS2: Renner-Teller, spin-orbit, and K-resonance effects.

The lowest-lying vibronic levels of the X, A, and B states of BS2 have been investigated at high resolution using a combination of room-temperature absorption and supersonic jet data. In both cases, the BS2 radical was prepared in an electric discharge using a precursor gas mixture of BCl3,CS2, and either helium or argon. Extensive absorption spectra were obtained for the 0(0)0 and 2(1)1 bands of the A2pi(u)-X2pi(g) electronic transition in the visible.

The first observation of the rhodium monofluoride molecule: jet-cooled laser spectroscopic studies.

Rhodium monofluoride has been observed and spectroscopically characterized. RhF molecules were produced under jet-cooled conditions in a laser vaporization molecular beam source by the reaction of a laser-vaporized rhodium plasma with SF(6) doped in helium, and studied with laser-induced fluorescence spectroscopy under both medium and high resolution. More than 25 bands have been observed in laser-induced fluorescence between 18,500 and 24,500 cm(-1) and five of these have been recorded at 200 MHz resolution.

Phosphorus hyperfine structure in the electronic spectrum of the HPCl free radical.

The 444 nm 2 0 (1) bands of the A 2A'-X 2A" transition of the jet-cooled HP 35Cl and HP 37Cl radicals have been studied at high resolution using the pulsed electric discharge technique with a precursor mixture of PCl3 and H2. Spectra recorded with linewidths of approximately 360 MHz revealed resolved hyperfine structure in both isotopomers arising from the excited state Fermi contact interaction of the unpaired electron with the magnetic moment of the 31P nucleus, with aF'=0.0641(10) cm(-1) and 0.