Publications by authors named "Aliyah S Alhawiti"

Algal enzymes are essential catalysts in numerous biological reactions and industrial processes owing to their adaptability and potency. The marketing of algal enzymes has recently risen due to various reasons, including the cost-efficient manner of their cultivation in photobioreactors, the eco-friendly production of high biomass contents, sources of novel enzymes that used in many sectors (biofuel and bioremediation applications), sustainability, and more renewability. Oxidoreductases and hydrolytic enzymes are among the important applied algal enzymes in industrial applications, with annually growing demand.

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Developing a sorbent for the removal of La ions from wastewater offers significant environmental and economic advantages. This study employed an ion-imprinting process to integrate La ions into a newly developed derivative of aminoguanidine-chitosan (AGCS), synthesized via an innovative method. The process initiated with the modification of chitosan by attaching cyanoacetyl groups through amide bonds, yielding cyanoacetyl chitosan (CAC).

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Article Synopsis
  • The AcPase enzyme has a high specific activity of 31.32 U/mg with significant purification and a low yield of 3.15% compared to the Zn-dependent variant which has a lower specific activity of 14 U/mg and higher total recovery at 5.14%.
  • SDS-PAGE analysis shows a single band for each enzyme, with AcPase at 18 kDa and Zn-AcPase at 29 kDa, indicating their molecular weights.
  • AcPase shows broad substrate specificity, while Zn-AcPase shows preference for certain substrates, and various divalent metal ions enhance enzyme activity, while others inhibit it; competitive inhibitors have been identified for both enzyme types,
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In the current work, an enantioselective imprinting technique was used to develop a very selective adsorbent for the (+)-cathine ((+)-Cat) enantiomer. The phenolic sulfonamide produced from 2,4-dihydroxybenzenesulfonic acid (HBS) and (+)-Cat ((+)-Cat-HBS) was initially synthesized by triphenylphosphene activation and subsequently involved in condensation polymerization with resorcinol in the presence of formaldehyde under acidic conditions. Alkaline sulfonamide bond-breaking was subsequently employed to separate the (+)-Cat template from the polymer, and the resulting imprinted resin ((+)-CIP) displayed high selectivity for the (+)-Cat, with a capacity of 225 ± 2 mg/g.

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Using microwave technique in the presence of citric acid, selenium nanoparticles (SeNPs) were fabricated. The morphological characteristics revealed that the spherical SeNPs with diameters ranging from 10.5 to 20 nm aggregated spherical shapes with sizes ranging from 0.

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The main aim of this work is the preparation of azo dye modified chitosan that was subsequently used in the ion-imprinting of Cr(III) ions to finally obtain ion-selective sorbent able to selectively combine with Cr(III) ions from water when coexisting with other similar metal ions. The azo dye derived from resorcinol and p-aminobenzoic acid was prepared and then linked to the chitosan amino groups by amide linkages utilizing EDC/NHS coupling agent. A polymeric complex of the azo dye chitosan derivative AZCS and Cr(III) ions was then prepared and treated with glyoxal solution, which cross-link the main chitosan chains in form of micro-spherical beads in presence of the coordinated Cr(III) ions that were later expelled out of the texture of the beads using acidified EDTA eluent solution while preserving the spatial and geometrical shape of the resulting Cr(III) ions chelating sites.

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