Facile Tuning of the Surface Energy of Cellulose Nanofibers for Nanocomposite Reinforcement.

The isolation of nanocellulose from lignocellulosic biomass, with desirable surface chemistry and morphology, has gained extensive scientific attention for various applications including polymer nanocomposite reinforcement. Additionally, environmental and economic concerns have driven researchers to explore viable alternatives to current isolation approaches, employing chemicals with reduced environmental impact. To address these issues, in this study, we have tuned the amphiphilic behavior of cellulose nanofibers (CNFs) by employing controlled alkali treatment, instead of in combination with expensive, environmentally unsustainable conventional approaches.

Atomic Layer Deposition of Metal Oxide on Nanocellulose for Enabling Microscopic Characterization of Polymer Nanocomposites.

Analysis of cellulose nanocrystals (CNCs) at low volume fractions in polymer nanocomposites through conventional electron microscopy still remains a challenge due to insufficient contrast between CNCs and organic polymer matrices. Herein, a methodology for enhancing the contrast of CNC, through atomic layer deposition (ALD) of alumina (Al O ) on CNCs is demonstrated. The metal oxide coated CNC allows clear visualization by transmission electron microscopy, when they are dispersed in water and polyol.

Reinforcement of natural rubber latex using lignocellulosic nanofibers isolated from spinifex grass.

Reinforcement of natural rubber (NR) using nanofillers often results in an enhancement of the tensile strength, but at the expense of elongation at break and toughness. In this study, with the objective of strengthening NR without compromising its compliance, we investigate the reinforcement efficiency of a series of cellulose nanofibers (CNF) with variations in residual hemicellulose, lignin and therefore surface chemistry. Different types of high aspect ratio CNF isolated from Triodia pungens (T.