Chiral Symmetry Breaking in Colloidal Metal Nanoparticle Solutions by Circularly Polarized Light.

Shape symmetry breaking in the formation of inorganic nanostructures is of significant current interest. It was typically achieved through the growth of colloidal nanoparticles with adsorbed chiral molecules. Photochemical processes induced through asymmetric plasmon excitation by circularly polarized light in surface immobilized nanostructures also led to symmetry breaking.

Impact of Surface Ligand on the Biocompatibility of InP/ZnS Quantum Dots with Platelets.

InP/ZnS quantum dots (QDs) have received a large focus in recent years as a safer alternative to heavy metal-based QDs. Given their intrinsic fluorescent imaging capabilities, these QDs can be potentially relevant for in vivo platelet imaging. The InP/ZnS QDs are synthesized and their biocompatibility investigated through the use of different phase transfer agents.

Nonclassical Mechanism of Metal-Enhanced Photoluminescence of Quantum Dots.

Metal-enhanced photoluminescence is able to provide a robust signal even from a single emitter and is promising in applications in biosensors and optoelectronic devices. However, its realization with semiconductor nanocrystals (e.g.

Magnetic Mode Coupling in Hyperbolic Bowtie Meta-Antennas.

Hyperbolic metaparticles have emerged as the next step in metamaterial applications, providing tunable electromagnetic properties on demand. However, coupling of optical modes in hyperbolic meta-antennas has not been explored. Here, we present in detail the magnetic and electric dipolar modes supported by a hyperbolic bowtie meta-antenna and clearly demonstrate the existence of two magnetic coupling regimes in such hyperbolic systems.

Parametric study of the silver nanoparticles deposition on polyelectrolyte supporting layers.

Colloidal nanoparticles deposition on polyelectrolyte (PE) supporting layers is a widespread technique to achieve high density nanoparticle coatings, however the choice of the parameters is often not consistent and varies in different reports. Frequently the obtained films suffer from the aggregation and non-reproducibility. Here, we addressed the main variables in silver nanoparticles deposition-the immobilization time; concentration of the PE in the solution; the thickness of PE underlayer and overlayer; the concentration of salt in the PE solution during the formation of a underlayer.

Engineering of the Photon Local Density of States: Strong Inhibition of Spontaneous Emission near the Resonant and High-Refractive Index Dielectric Nano-objects.

Metallic or dielectric nano-objects change the photon local density of states of closely placed emitters, particularly when plasmon or Mie resonances are present. Depending on the shape and material of these nano-objects, they may induce either a decrease or an increase in decay rates of the excited states of the emitter. In this work, we consider the reduction of the probability of optical transitions in emitters near high-refractive index dielectric (silicon and zinc selenide) nanoparticles.

Influence of the CTAB surfactant layer on optical properties of single metallic nanospheres.

We evaluate experimentally and theoretically the role of the residual ligands and ambient environment refractive index in the optical response of a single spherical gold nanoparticle on a substrate and demonstrate the changes in the near- and far-field properties of its hybridized modes in the presence of the cetyltrimethylammonium bromide (CTAB) layer. Particularly, we show that the conventional bilayer scheme for CTAB is not relevant for colloidal nanoparticles deposited on a substrate. We show that this CTAB layer considerably changes the amplitude and localization of the confinement of the electric field, which is of prime importance in the design of plasmonic complex systems coupled to emitters.

Plasmon-enhanced fluorescence in gold nanorod-quantum dot coupled systems.

Plasmon-exciton coupling is of great importance to many optical devices and applications. One of the coupling manifestations is plasmon-enhanced fluorescence. Although this effect is demonstrated in numerous experimental and theoretical works, there are different particle shapes for which this effect is not fully investigated.

Possible nanoantenna control of chlorophyll dynamics for bioinspired photovoltaics.

In the context of using portions of a photosynthetic apparatus of green plants and photosynthesizing bacteria in bioinspired photovoltaic systems, we consider possible control of the chlorophyll excited state decay rate using nanoantennas in the form of a single metal and semiconductor nanoparticle. Since chlorophyll luminescence competes with electron delivery for chemical reactions chain and also to an external circuit, we examine possible excited state decay inhibition contrary to radiative rate enhancement. Both metal and semiconductor nanoparticles enable inhibition of radiative decay rate by one order of the magnitude as compared to that in vacuum, whereas a metal nanosphere cannot perform the overall decay inhibition since slowing down of radiative decay occurs only along with the similar growth of its nonradiative counterpart whereas a semiconductor nanoantenna is lossless.

Enhanced Raman scattering of ZnO nanocrystals in the vicinity of gold and silver nanostructured surfaces.

nonresonant surface enhanced Raman scattering by optical phonons of ZnO nanocrystals on and beneath silver and gold island films is reported. For both configurations comparable SERS efficiency is observed, proving their potential utility. Variations in peak intensities can be attributed to difference in the morphology of island films on and beneath nanocrystals as well as to variation of the interface between semiconductor and metal.