Enhanced photocatalytic treatment using plasmonic AgAgPO/AgAgCl nanophotocatalyst for simultaneous degradation of multiple parabens and UV-filters in various aquatic environments under visible light irradiation.

In this study, simultaneous photocatalytic degradation of different parabens (methyl-, ethyl-, propyl-, and butyl paraben) and UV filters (benzophenone-3, 4-methylbenzylidene camphor, 2-ethylhexyl 4-(dimethylamino) benzoate, ethylhexyl methoxycinnamate and octocrylene) in water matrices was performed under visible light irradiation using novel double plasmonic AgAgPO/AgAgCl nanophotocatalyst, synthesized by an easy and fast photochemical conversion and photo-reduction. It was found that the nanophotocatalyst with appropriate mole ratio of AgAgPO/AgAgCl (1:3) showed superior photocatalytic activity than individual plasmonic nanoparticles. This is because there are two simultaneous surface plasmon resonances (SPR) generated by the metallic Ag nanoparticles, in addition to the hetero-junction structure formed at the interface between AgAgPO and AgAgCl.

Recovery of Persipeptides from Fermentation Broth by Enhanced Adsorption.

Background: Drug discovery process is growing considerably due to the noteworthy resource of natural products. Persipeptides A and B are cyclopeptide antibiotics, which are produced by UTMC 1154. Although extraction of culture broth with the help of solvent has been optimized previously, no effort for extraction of persipeptides has been done yet.

New BiMoO nano-shapes toward ultrasensitive enzymeless glucose tracing: Synergetic effect of the Bi-Mo association.

In a novel approach, an efficient non-enzymatic glucose sensor based on pure phase of aurivillius bismuth molybdate (BM or γ-BiMoO) mixed metal oxides is reported. Three BM samples were synthesized, with/without l-cysteine (Cys) and dodecylamine (DDA) as additives, leading to different shapes: bullet (BM-C), confetti (BM-2Cys) and candy (BM-2DDA). The morphology and purity of the structures were confirmed by FE-SEM images and XRD.

Cetyltrimethylammonium Bromide (CTAB) Bloated Micelles and Merged CTAB/Bolaamphiphiles Self-Assembled Vesicles toward the Generation of Highly Porous Alumina as Efficacious Inorganic Adsorbents.

Herein, in a new approach, highly porous alumina materials (HiPAs) have been synthesized through cetyltrimethylammonium bromide (CTAB) bloated micelles or merged CTAB/dicarboxylic acid vesicular aggregates (di-acids with 8, 10, and 12 carbon atoms) as novel templates and characterized by N sorption, low- and wide-angle XRD (X-ray diffraction), FE-SEM (field emission scanning electron microscopy), TEM (transmission electron microscopy), HR-TEM (high-resolution transmission electron microscopy), DLS (dynamic light scattering), and AFM (atomic force microscopy) analyses. In the absence of dicarboxylic acids, CTAB bloated micelles in ethanol-aqueous solutions were conductive to the formation of mesoporous γ-alumina hollow spheres (HiPA-CT) with high surface area (394 m g) and ultralarge pore volume (1.8 cm g).

Anticancer activity of new imidazole derivative of 1R,2R-diaminocyclohexane palladium and platinum complexes as DNA fluorescent probes.

The aim of this study was synthesis of two new water-soluble fluorescent palladium and platinum complexes with formulas of [Pt(DACH)(FIP)](NO) and [Pd(DACH)(FIP)](NO), respectively, where FIP is 2-(furan-2-yl)-1H-imidazo[4,5-f][1,10] phenanthroline and DACH is 1R,2R-diaminocyclohexane. Fluorescence spectroscopy, circular dichroism (CD), thermal denaturation measurement, ionic strength, and kinetic study displayed groove binding of Pt complex on DNA, while due to binding of Pd complex, B form of DNA convert to Z form. Due to electrostatic interaction of Pd complex with DNA, the DNA form is converted and it provides enough space for Pd complex to insert between base stacking of DNA.

Application of Metal-Organic Framework Nano-MIL-100(Fe) for Sustainable Release of Doxycycline and Tetracycline.

Nanostructures of MIL-100 were synthesized and used as a drug delivery platform for two members of the Tetracycline family. Doxycycline monohydrate (DOX) and Tetracycline hydrochloride (TC) were loaded separately on nano-MIL-100 (nanoparticles of drug@carrier were abbreviated as DOX@MIL-100 and TC@MIL-100). Characterizations were carried out using FT-IR, XRD, BET, DLS, and SEM.

DNA as a Target for Anticancer Phen-Imidazole Pd(II) Complexes.

Imidazole ring is a known structure in many natural or synthetic drug molecules and its metal complexes can interact with DNA and do the cleavage. Hence, to study the influence of the structure and size of the ligand on biological behavior of metal complexes, two water-soluble Pd(II) complexes of phen and FIP ligands (where phen is 1,10-phenanthroline and FIP is 2-(Furan-2-yl)-1H-Imidazo[4,5-f][1, 10]phenanthroline) with the formula of [Pd(phen)(FIP)](NO) and [Pd(FIP)]Cl, that were activated against chronic myelogenous leukemia cell line, K562, were selected. Also, the interaction of these anticancer Pd(II) complexes with highly polymerized calf thymus DNA was extensively studied by means of electronic absorption, fluorescence, and circular dichroism in Tris-buffer.

Multivalent calix[4]arene-based fluorescent sensor for detecting silver ions in aqueous media and physiological environment.

A new derivative of dipodal 1,3-calix[4]arene-based chemosensor (R), which was containing several binding sites have been synthesized and characterized by NMR, IR and LC-MS spectroscopic methods. The selectivity of Rhas been investigated in aqueous methanol, resulting in fluorescence shift and selective recognition of Ag among 20 various alkali, alkaline earth and transition metal ions. Microstructural features of R and its complex with Aghave been investigated by Atomic Force Microscopy (AFM).

New ZnO nanostructures as non-enzymatic glucose biosensors.

In a new approach, shape controlled synthesis of zinc oxide nanostructures were carried out using a solvothermal route assisted amino acids such as L-Lysine (lysine), L-Cysteine (cysteine) and L-Arginine (arginine) as bifunctional species with (or without) urea or oxalic acid as additives which affect the pH of the reaction. Rod, powder, particle, cube, rock candy-like, sheet, sphere, brain-like, groundnut-like and pussy willow-like morphologies were obtained through the synthetic route. Particle sizes varied from 25 nm to4 μm.

Immobilization of Keggin and Preyssler tungsten heteropolyacids on various functionalized silica.

The Keggin and Preyssler tungsten heteropolyacids, H3PW12O40 and H15P5W30O110, have been immobilized on the inner surface of mesoporous MCM-41, fume silica and silica-gel by means of chemical bonding to aminosilane groups. The materials were characterized by FT-IR spectroscopy, low-angle XRD and BET surface area analysis. The tendencies of heteropolyacids adsorption in solution on functionalized silicas have been investigated by UV-vis.

Novel method for the fast preconcentration and monitoring of a ppt level of lead and copper with a modified hexagonal mesoporous silica compound and inductively coupled plasma atomic emission spectrometry.

A novel method for the rapid extraction and determination of a ppt level of Pb2+ and Cu2+ ions using partial silylated MCM-41 modified by a new salophen and inductively coupled plasma atomic emission spectrometry (ICP-AES) is introduced. The preconcentration factor of the method is 500, and the detection limits of Pb2+ and Cu2+ are 335 and 34 ng L(-1), respectively. The time and efficiency of extraction, the pH and flow rate, the type and minimum amount of acid for stripping of Pb2+ and Cu2+ from modified MCM-41 and the break-through volume were investigated.