Various Morphologies of Graphitic Carbon Nitride (g-CN) and Their Effect on the Thermomechanical Properties of Thermoset Epoxy Resin Composites.

This research aims to highlight the importance of diverse forms of graphitic carbon nitride (g-CN) as strengthening elements in epoxy composites. It explores the influence of three different forms of g-CN and their concentrations on the mechanical properties of the epoxy composites. Various characterization techniques, such as scanning electron microscopy (SEM), dynamic light scattering (DLS), thermogravimetric analysis (TGA), and Fourier-transform infrared spectroscopy (FTIR), were utilized to comprehend the effects of g-CN morphology and particle size on the physical and chemical characteristics of epoxy resin.

Cellulose Functionalization Using -Heterocyclic-Based Leaving Group Chemistry.

There has been continuous interest in developing novel activators that facilitate the functionalization of cellulosic materials. In this paper, we developed a strategy in which trisubstituted triazinium salts act as cellulose preactivators. As leaving groups, these triazinium salts utilize -heterocycles (pyridine, imidazole, and nicotinic acid).

Self-Healability of Poly(Ethylene-co-Methacrylic Acid): Effect of Ionic Content and Neutralization.

Self-healing polymers such as poly(ethylene-co-methacrylic acid) ionomers (PEMAA) can heal themselves immediately after a projectile puncture which in turn lowers environmental pollution from replacement. In this study, the thermal-mechanical properties and self-healing response of a library of 15 PEMAA copolymers were studied to understand the effects of the ionic content (Li, Na, Zn, Mg) and neutralization percentage (13 to 78%) on the results. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and tensile testing were used to study the thermo-mechanical properties of PEMAA copolymers while the self-healing response was studied using the projectile test.

Application of Achillea millefolium extract as a reducing agent for synthesis of silver nanoparticles (AgNPs) on the cotton: antibacterial, antioxidant and dyeing studies.

The phyto-synthesis of silver nanoparticles and cotton dyeing with natural colorants can reduce the environmental impact of the process considerably. In this study, the extraction of natural colorants from Achillea millefolium petals was optimized by ultrasound technique. The AMP extract was applied for synthesis of silver nanoparticles (Ag NPs) on the cotton fabrics.

Eco-Friendly Procedure for Rendering the Antibacterial and Antioxidant of Cotton Fabrics Phyto-Synthesized AgNPs With (MS) Natural Colorant.

There is a growing interest for producing multifunctional cellulose fabrics using green and sustainable technology. In this study, we explored an eco-friendly procedure for dyeing cotton fabrics with (MS) as a natural colorant and rendering antibacterial cotton fabric by the silver nanoparticles. MS colorants were extracted from dried petals in water using the ultrasound technique, cotton fabrics were dyed with the extracted MS colorant at 100°C for 90 min.

Surface characterization of thin-film composite membranes using contact angle technique: Review of quantification strategies and applications.

Thin-film composite (TFC) membranes are the most widely used membranes for low-cost and energy-efficient water desalination processes. Proper control over the three influential surface parameters, namely wettability, roughness, and surface charge, is vital in optimizing the TFC membrane surface and permeation properties. More specifically, the surface properties of TFC membranes are often tailored by incorporating novel special wettability materials to increase hydrophilicity and tune surface physicochemical heterogeneity.

Synthesis of Palladium Nanodendrites Using a Mixture of Cationic and Anionic Surfactants.

Surfactants are used widely to control the synthesis of shaped noble-metal nanoparticles. In this work, a mixture of hexadecyltrimethylammonium bromide (CTAB), a cationic surfactant; sodium oleate (NaOL), an anionic surfactant; palladium chloride; and a reducing agent were used in the seed-mediated synthesis of palladium nanoparticles. By controlling the surfactant mixture ratio, we initially discovered that palladium nanodendrites with narrow size distribution were formed instead of the traditional nanocubes, synthesized with only CTAB.

Waterproof breathable layers - A review.

Waterproof breathable layers (WPBLs) can be classified into two large groups of hydrophilic nonporous and hydrophobic porous layers. These layers (e.g.

Mesoscopically ordered bone-mimetic nanocomposites.

A sustainable approach that highly mimics bone-material deposition is reported to produce mechanically stable, degradable composites with nanostructures resembling that of natural bone. Molecular self-assembly combining intermolecular crosslinking leads to resilient matrices possessing long-range ordered aqueous domains, inside which moderately aligned poorly crystalline apatite is converted from the transient amorphous calcium phosphate phase.

Epoxy resin monomers with reduced skin sensitizing potency.

Epoxy resin monomers (ERMs), especially diglycidyl ethers of bisphenol A and F (DGEBA and DGEBF), are extensively used as building blocks for thermosetting polymers. However, they are known to commonly cause skin allergy. This research describes a number of alternative ERMs, designed with the aim of reducing the skin sensitizing potency while maintaining the ability to form thermosetting polymers.

Micelle growth of cationic gemini surfactants studied by NMR and by time-resolved fluorescence quenching.

The micelle growth of a series of five cationic gemini surfactants has been investigated by time-resolved fluorescence quenching (TRFQ) and by two NMR techniques, line width analysis and diffusometry. The surfactant series was designed such that the effect of a number of variables could be assessed: length of the spacer unit, presence of ester bonds in the tails close to the head groups, and presence of a hydroxyl group in the spacer. For the gemini with long spacer, the micelles remained relatively small in size upon an increase of the concentration.

Solubilization of Hydrophobic Dyes in Surfactant Solutions.

In this paper, the use of surfactants for solubilization of hydrophobic organic dyes (mainly solvent and disperse dyes) has been reviewed. The effect of parameters such as the chemical structures of the surfactant and the dye, addition of salt and of polyelectrolytes, pH, and temperature on dye solubilization has been discussed. Surfactant self-assemble into micelles in aqueous solution and below the concentration where this occurs-the critical micelle concentration (CMC)-there is no solubilization.