Harvesting solar energy, as a clean and abundant resource, in the photothermal process, is the winning point of solar steam generation (SSG) systems. Herein, copper plasmonic nanoparticles were synthesized through a green method via red sanders extraction on the cotton fabric as the reducing matrix. The prepared fabrics were analyzed using FESEM, EDS, XRD, PL, Raman, and contact angle.
View Article and Find Full Text PDFMicromachines (Basel)
November 2022
Due to the favorable properties of two-dimensional materials such as SnS with an energy gap in the visible light spectrum, and InSe, with high electron mobility, the combination of them can create a novel platform for electronic and optical devices. Herein, we study a tunable gain SnS/InSe Van der Waals heterostructure photodetector. SnS crystals were synthesized by chemical vapor transport method and characterized using X-ray diffraction and Raman spectroscopy.
View Article and Find Full Text PDFSelf-powered detectors based on triboelectric nanogenerators (TENG) have been considered because of their capability to convert ambient mechanical energy to electrical out-put signal, instead of conventional usage of electrochemical batteries as power sources. In this regard, the self-powered photodetectors have been designed through totally two lay out called passive and active circuit. in former model, impedance matching between the TENG and the resistance of the circuit's elements is crucial, which is not investigated systematically till now.
View Article and Find Full Text PDFHigh-performance photodetectors play crucial roles as an essential tool in many fields of science and technology, such as photonics, imaging, spectroscopy, and data communications. Demands for desired efficiency and low-cost new photodetectors through facile manufacturing methods have become a long-standing challenge. We used a simple successive ionic layer adsorption and reaction (SILAR) method to synthesize CdS, CdSe, and PbS nanoparticles directly grown on WSe crystalline flakes.
View Article and Find Full Text PDFSynthesizing efficient electrode materials for water splitting and supercapacitors is essential for developing clean electrochemical energy conversion/storage devices. In the present work, we report the construction of a ruthenium cobalt oxide (RuCoO)/TiCT MXene hybrid by electrophoretic deposition of TiCT MXene on nickel foam (NF) followed by RuCoO nanostructure growth through an electrodeposition process. Owing to the strong interactions between RuCoO and TiCT sheets, which are verified by density functional theory (DFT)-based simulations, RuCoO/TiCT MXene@NF can serve as a bifunctional electrode for both water splitting and supercapacitor applications.
View Article and Find Full Text PDFTwo-dimensional (2D) transition metal dichalcogenides are promising candidates of photodetectors where they are commonly grown parallel to the substrate due to their 2D characteristics in micrometer scales from exfoliation of bulk crystals or through high temperature chemical vapor deposition (CVD) methods. In this study, semi-hexagonal vertical nanosheets of SnS layered have been fabricated on FTO substrate without using Sn source through CVD method at relatively low temperature (500 °C). Due to exceptional band alignment of triple cation lead perovskite (TCLP) with semi-hexagonal SnS nanosheets, an improved photodetector has been fabricated.
View Article and Find Full Text PDFDyes molecules are the most common pollutants of wastewater in the environment from the textile industry to numbers of technologies include dyeing, printing, and painting procedures. Among membrane-based separation approaches as established methods in the water treatment industry, polymers attracted massive attention in the production of membranes due to their low cost and high-performance filtration of pollutants. However, hydrophobicity and low speed of filtration along with limited decontamination performance against some of the dyes, demand new approaches and membranes to overcome drawbacks points.
View Article and Find Full Text PDFGraphene nanoribbons (GNRs) fabricated using electron beam lithography are investigated using tip-enhanced Raman spectroscopy (TERS) with a spatial resolution of 5 nm under ambient conditions. High-resolution TERS imaging reveals a structurally modified 5-10 nm strip of disordered graphene at the edge of the GNRs. Furthermore, hyperspectral TERS imaging discovers the presence of nanoscale organic contaminants on the GNRs.
View Article and Find Full Text PDFEnhancing the photoresponse of single-layered semiconductor materials is a challenge for high-performance photodetectors due to atomically thickness and limited quantum efficiency of these devices. Band engineering in heterostructure of transition metal chalcogenides (TMDs) can sort out part of this challenge. Here, we address this issue by utilizing the plasmonics phenomenon to enrich the optoelectronics property of the WSe/MoSheterojunction and further enhancement of photoresponse.
View Article and Find Full Text PDFDecoding behavioral aspects associated with the water molecules in confined spaces such as an interlayer space of two-dimensional nanosheets is key for the fundamental understanding of water-matter interactions and identifying unexpected phenomena of water molecules in chemistry and physics. Although numerous studies have been conducted on the behavior of water molecules in confined spaces, their reach stops at the properties of the planar ice-like formation, where van der Waals interactions are the predominant interactions and many questions on the confined space such as the possibility of electron exchange and excitation state remain unsettled. We used density functional theory and reactive molecular dynamics to reveal orbital overlap and induction bonding between water molecules and graphene sheets under much less pressure than graphene fractures.
View Article and Find Full Text PDFThe room temperature polar vapor sensing behavior of a graphene-TiS heterojunction material and TiS nanoribbons is described. The nanoribbons were synthesized via chemical vapor transport (CVT) and their structure was investigated by scanning electron microscopy, high resolution transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, Raman and Fourier transform infrared spectroscopies. The gas sensing performance was assessed by following the changes in their resistivities.
View Article and Find Full Text PDFA chemiresistive sensor is described for the lung cancer biomarker hexanal. A composite consisting of molecularly imprinted polymer nanoparticles and multiwalled carbon nanotubes was used in the sensor that is typically operated at a voltage of 4 V and is capable of selectively sensing gaseous hexanal at room temperature. It works in the 10 to 200 ppm concentration range and has a 10 ppm detection limit (at S/N = 3).
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