Sensitivity Analysis in the Microkinetic Description of Electrocatalytic Reactions.

A methodology to determine how the variation in a kinetic parameter affects the global kinetic response of an electrochemical reaction is proposed. The so-called sensitivity analysis is applied to quantify the contribution of single reaction steps of an electrocatalytic system under an oscillatory regime using microkinetic analysis.

Phase diagrams and dynamical evolution of the triple-pathway electro-oxidation of formic acid on platinum.

Recently, an electro-kinetic model based on a specified reaction scheme for the electro-oxidation of formic acid on platinum was reported. The model evaluated three reaction pathways towards the production of CO2: the dehydrogenation and the dehydration of formic acid, and the third and most active pathway includes fast oxidation of the formate ion. Numerical integrations showed that the model is well-suited to describe the experimental results in voltammetric and oscillatory regimes.