Mixed potassium-manganese vanadate-carbonate, K(2)Mn(3)(VO(4))(2)(CO(3)), represents a novel structure type; it has been synthesized hydrothermally from the system MnCl(2)-K(2)CO(3)-V(2)O(5)-H(2)O. Its hexagonal crystal structure was determined by single-crystal X-ray diffraction with a = 5.201(1) Å, c = 22.
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