Modulating TTA efficiency through control of high energy triplet states.

An ideal annihilator in triplet-triplet annihilation photon upconversion (TTA-UC) can achieve a maximum of 50% quantum efficiency. This spin statistical limit depends on the energies of the triplet states of the annihilator molecule, with only 20% quantum efficiencies possible in less-optimal energy configurations ( ≤ 2 ). Our work utilises three perylene analogues substituted with phenyl in sequential positions.

Exciton Delocalization Counteracts the Energy Gap: A New Pathway toward NIR-Emissive Dyes.

Exciton coupling between the transition dipole moments of ordered dyes in supramolecular assemblies, so-called J/H-aggregates, leads to shifted electronic transitions. This can lower the excited state energy, allowing for emission well into the near-infrared regime. However, as we show here, it is not only the excited state energy modifications that J-aggregates can provide.

Interplay between Förster and Dexter Energy Transfer Rates in Isomeric Donor-Bridge-Acceptor Systems.

The ability to direct the flow of excitons enable molecular systems to perform highly advanced functions. Intramolecular energy transfer in donor-bridge-acceptor systems can occur by different mechanisms, and the ability to control the excited state energy pathways depends on the capacity to favor one process over another. Here, we show an anticorrelation between the rates of Förster and Dexter types of energy transfer in two isomeric donor-bridge-acceptor systems.