Acta Crystallogr E Crystallogr Commun
February 2018
In the title coordination polymer, {[CuCl(CHNOS)]·CHCN} , the copper(II) ion is fivefold coordinated, with an almost perfect square-pyramidal coordination sphere. In the equatorial plane, it is ligated to a pyridine N atom and an N atom of the triazole unit and to two Cl ions, while the apical position is occupied by the carbonyl O atom of the -butyl carbamate group. In the crystal, the polymer chains propagate in the [11-1] direction, with the aceto-nitrile solvent mol-ecules linked to the chain by C-H⋯N hydrogen bonds.
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