Covalent Triazine Frameworks Based on the First -Octahedral Hexanitrile Monomer via Nitrile Trimerization: Synthesis, Porosity, and CO Gas Sorption Properties.

Herein, we report the first synthesis of covalent triazine-based frameworks (CTFs) based on a hexanitrile monomer, namely the novel pseudo-octahedral hexanitrile 1,4-bis(tris(4'-cyano-phenyl)methyl)benzene using both ionothermal reaction conditions with ZnCl at 400 °C and the milder reaction conditions with the strong Brønsted acid trifluoromethanesulfonic acid (TFMS) at room temperature. Additionally, the hexanitrile was combined with different di-, tri-, and tetranitriles as a second linker based on recent work of mixed-linker CTFs, which showed enhanced carbon dioxide captures. The obtained framework structures were characterized via infrared (IR) spectroscopy, elemental analysis, scanning electron microscopy (SEM), and gas sorption measurements.