Biosourced Au(III) Complexes from D-Xylose: Synthesis and Biological Evaluation.

A series of xylose-based ligands was obtained using a convenient approach, in a few steps from D-xylose. The complexation properties of these ligands towards Au cations have been studied through different methods (multinuclear NMR, mass spectrometry, elemental analysis). The biological properties (antibacterial and anti-tumoral) of all the isolated xyloside Au(III) complexes were investigated in vitro.

Pesticide sorption and mitigation efficiency of a detention pond in a Champagne vineyard catchment.

Detention ponds (DPs) are used to reduce the pesticide inputs from runoff to surface water. This study aimed to assess the role of the sorption process in the mitigation of a DP made up of four successive units and built at the outlet of a vineyard catchment in Champagne (France) to treat runoff waters. Sorption kinetics and isotherms were studied for four pesticides with contrasting properties, cyazofamid (CYA), fludioxonil (FLX), fluopicolide (FLP) and oryzalin (ORY), in the presence of copper in sediments and four emergent macrophyte roots and rhizomes sampled in the DP units 2 (photodegradation) and 3 (phytoremediation).