A fast one-pot synthesize of crystalline anglesite by hydrothermal synthesis for environmental assessment on pure phase.

Anglesite (PbSO) is a lead sulfate that belongs to the barite group and is naturally ubiquitous in the environment. This work describes a simple way to synthesize crystalline lead sulfate by using a straightforward hydrothermal procedure. Typically, Pb(NO) and Fe(SO) precursors were mixed and heated at 94 °C for 24 h.

Investigating the relationship between speciation and oral/lung bioaccessibility of a highly contaminated tailing: contribution in health risk assessment.

Anthropogenic activities such as industrial, mining, or agricultural are the main sources of environmental contamination. One of the most problematic contaminations concerns metals and metalloids from mining activities. This contamination raises the question of the environmental risk induced and the spread of this pollution (geographical and trophic) and the associated health risk.

Environmental stability and oral bioaccessibility of synthetic Pb-bearing phases to better evaluate soil health risks.

A large amount of contaminated sites is shown around the world which may induce a health risk due to the presence of contaminants such as metal (loïd)s bearing phases. Health risk assessment is based on contaminant bioaccessibility. However, it is needed to understand every contaminant behavior in physiological matrix to be a realistic way to assess and interpret these sanitary risks.

Key parameters influencing metallic element mobility associated with sediments in a daily-managed reservoir.

In a hydroelectric reservoir, sediments are subject to remobilization events, water-level fluctuations and physicochemical changes. Depending on their associated metallic content, surficial oxic to suboxic sediments could constitute a major source of metals. To identify the key parameters that control metallic elements in terms of their mobility and sensitivity to reservoir management, sediments were subject to resuspension and drying/wetting cycle experiments over a wide range of pH values, solid/liquid ratios (S/L) and redox (Eh) conditions.

Phosphate removal from aqueous solution using ZVI/sand bed reactor: Behavior and mechanism.

This research reports on phosphate removal from aqueous solution using ZVI/sand packed columns. The influence of column preconditioning, consisting of ZVI pre-oxidation before feeding the columns with phosphate solution, revealed that a column aged for 1 day was more efficient than un-conditioned column, 5-days and 10-days preconditioned columns. The distribution of phosphate trapped inside the columns was evaluated by measuring phosphate concentration in the solids at different levels (P1, P2 and P3) along the depth of the columns.

Impact of sediments resuspension on metal solubilization and water quality during recurrent reservoir sluicing management.

In dam contexts, sluicing operations can be performed to reestablish sediments continuity, as proposed by the EU Water Framework Directive, as well as to preserve the reservoirs' water storage capacity. Such management permits the rapid release of high quantities of reservoir sediments through the opening of dam bottom valves. This work aims to study the impact of such operation on the evolution of environmental physicochemical conditions notably changes in dissolved metallic elements concentrations (Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn) through field and laboratory investigations.

Influence of dams on sediment continuity: A study case of a natural metallic contamination.

Sediments play an important role on the quality of aquatic ecosystems, notably in the reservoir areas where they can either be a sink or a source of contaminants, depending on the management and hydrological conditions. The physicochemical properties of 25 surface sediments samples of a reservoir catchment (Vaussaire, Cantal, France) were studied. Results show a strong influence of dam presence, notably on the grain size and organic matter (OM) contents.

Evidence for the incorporation of lead into barite from waste rock pile materials.

Because Pb is one of the most toxic elements and is found as a major contaminant in mining environments, this study aims to identify the distribution of this element in host phases issued from the alteration of mine wastes. The sampling location was a former mine near Oakland, California (USA). This mine was once a source of sulfide minerals from which sulfuric acid was made.