Ultrathin Two-dimensional Layered Composite Carbosilicates from in situ Unzipped Carbon Nanotubes and Exfoliated Bulk Silica.

A key task in today's inorganic synthetic chemistry is to develop effective reactions, routes, and associated techniques aiming to create new functional materials with specifically desired multilevel structures and properties. Herein, we report an ultrathin two-dimensional layered composite of graphene ribbon and silicate via a simple and scalable one-pot reaction, which leads to the creation of a novel carbon-metal-silicate hybrid family: carbosilicate. The graphene ribbon is in situ formed by unzipping carbon nanotubes, while the ultrathin silicate is in situ obtained from bulk silica or commercial glass; transition metals (Fe or Ni) oxidized by water act as bridging agent, covalently bonding the two structures.

Insights into the electronic structure of hydroxyl on Ag(110) under near ambient conditions.

Adsorbed hydroxyl is a key intermediate present in many catalytic reactions and electrochemical processes. In particular, hydroxyl adsorbed on noble metal surfaces has attracted attention due to its role in water-gas shift, selective oxidation of hydrocarbons and water splitting. In this work, from a well-defined oxygen covered Ag(110) surface with O-(2 × 1) reconstruction, we prepared a fully hydroxylated surface phase in equilibrium with water and oxygen in the gas phase under near ambient conditions.

Near-Ambient Pressure XPS and MS Study of CO Oxidation over Model Pd-Au/HOPG Catalysts: The Effect of the Metal Ratio.

In this study, the dependence of the catalytic activity of highly oriented pyrolytic graphite (HOPG)-supported bimetallic Pd-Au catalysts towards the CO oxidation based on the Pd/Au atomic ratio was investigated. The activities of two model catalysts differing from each other in the initial Pd/Au atomic ratios appeared as distinctly different in terms of their ignition temperatures. More specifically, the PdAu-2 sample with a lower Pd/Au surface ratio (~0.

Investigation of Electrocatalysts Produced by a Novel Thermal Spray Deposition Method.

Common methods to produce supported catalysts include impregnation, precipitation, and thermal spray techniques. Supported electrocatalysts produced by a novel method for thermal spray deposition were investigated with respect to their structural properties, elemental composition, and electrochemical performance. This was done using electron microscopy, X-ray photoelectron spectroscopy, and cyclic voltammetry.

Are multiple oxygen species selective in ethylene epoxidation on silver?

The nature of the oxygen species active in ethylene epoxidation is a long-standing question. While the structure of the oxygen species that participates in total oxidation (nucleophilic oxygen) is known the atomic structure of the selective species (electrophilic oxygen) is still debated. Here, we use both and UHV X-ray Photoelectron Spectroscopy (XPS) to study the interaction of oxygen with a silver surface.

A near ambient pressure XPS study of Au oxidation.

The surface of a gold foil under ozone oxidation was examined by near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) and scanning electron microscopy (SEM). Our in situ observations show that a surface oxide phase is formed during the exposure to ozone; however this phase decomposes under vacuum and even in the presence of ozone at temperatures higher than 300 °C. Assuming that an oxide overlayer completely covers the Au surface, the thickness of the oxide phase was estimated to be between 0.