Publications by authors named "Alexander T Blumenau"
The translational and orientational potential energy surfaces (PESs) of n-alkanethiols with up to four carbon atoms are studied for (√(3)×√(3))R30° self-assembled monolayers (SAMs). The PESs indicate that methanethiol may form SAM structures that are not accessible for long-chain thiols. The tilt of the thiol molecules is determined by a compromise between the preferred binding geometry at the sulfur atom and the steric requirements of the alkane chains.
View Article and Find Full Text PDFArticle Synopsis
- The study examines how three adhesive components interact with the Al2O3 surface, focusing on their energy pathways and reaction energies using advanced computational techniques.
- Results indicate that the adhesion promoter AMEO is more likely to adsorb onto the surface compared to the resin DGEBA, while the curing agent DETA is not favored for adsorption.
- The methods used provide deeper insights into the mechanical and electronic effects of adsorption than traditional approaches, contributing to future research on organic/inorganic interfaces.