Synthesis of a lithium-cyclopentadienide complex by addition of LiNTf to a zwitterionic fulvalene.

The synthesis of a η-coordinated LiCp complex by simple addition of a Li-salt in benzene is presented. A strongly zwitterionic fulvalene serves as the Cp-precursor. Evidence for the coordination of Li was obtained by the characterisitic Li NMR chemical shifts, variable temperature experiments in solution and by X-ray structure analysis in the solid state.

A ligand substituted tungsten iodide cluster: luminescence vs. singlet oxygen production.

Octahedral tungsten iodide clusters equipped with apical ligands (L) are synthesized to implement substantial photophysical properties. The [WI(CFCOO)] cluster reported herein is the first example of a family of ligand substituted [WIL] clusters. Such compounds are expected to exhibit a rich photochemistry in which the apical ligands play a crucial role.