Architected Poly(ionic liquid) Composites with Spatially Programmable Mechanical Properties and Mixed Conductivity.

Structural electrolytes present advantages over liquid varieties, which are critical to myriad applications. In particular, structural electrolytes based on polymerized ionic liquids or poly(ionic liquids) (pILs) provide wide electrochemical windows, high thermal stability, nonvolatility, and modular chemistry. However, current methods of fabricating structural electrolytes from pILs and their composites present limitations.

An Application Exploiting Aurophilic Bonding and iClick to Produce White Light Emitting Materials.

The paper focuses on exploiting aurophilic bonding to produce white light emitting materials. Inorganic Click (iClick) is employed to link two or four Au(I) metal ions through a triazolate bridge. Depending on the choice of phosphine ligand (PEt or PPh), dinuclear Au-FO or tetranuclear Au-FO complexes can be controllably synthesized (FO = 2-(9,9-dioctylfluoreneyl-)).