Significantly Enhanced Balance of Dielectric Properties of Polyvinylidene Difluoride Three-Phase Composites by Silver Deposited on KNiTiO Hollandite Nanoparticles.

Three-phase polymer composites are promising materials for creating electronic device components. The qualitative and quantitative composition of such composites has a significant effect on their functional, in particular dielectric properties. In this study, ceramic filler KNiTiO (KNTO) with Ag coating as conductive additive (0.

Alcohol Vapor Sensor Based on Quasi-2D NbO Derived from Oxidized NbCT MXenes.

MXenes are two-dimensional (2D) materials with a great potential for sensor applications due to their high aspect ratio and fully functionalized surface that can be tuned for specific gas adsorption. Here, we demonstrate that the NbCT-based sensor exhibits high performance towards alcohol vapors at temperatures up to 300-350 °C, with the best sensitivity towards ethanol. We attribute the observed remarkable chemiresistive effect of this material to the formation of quasi-2D NbO sheets as the result of the oxidation of Nb-based MXenes.

Structure and Properties of the Xerogels Based on Potassium Silicate Liquid Glass and Urea.

The xerogels based on the aqueous solutions of urea in potassium silicate liquid glass (PSLG) were produced by CO bubbling and investigated. The structure and chemical composition of the obtained materials were analyzed. Using the SEM, XRD, IR-FT, DSC, and low energy local EDS analysis, it was recognized that the dried gels (xerogels) contained three forms of urea: oval crystals of regular shape appeared onto the surface of xerogel particles; fibrous crystals were located in the silicate matrix; and molecules/ions were incorporated into the silicate matrix.

Catalytic Decomposition of HO in the Aqueous Dispersions of the Potassium Polytitanates Produced in Different Conditions of Molten Salt Synthesis.

It is shown that the potassium polytitanate powder (PPT) synthesized at 500 °C via the treatment of powdered TiO (rutile) in molten mixtures of KOH and KNO is a cheap and effective catalyst of HO chemical decomposition in aqueous solutions. At the same time, the PPT catalytic activity strongly depends on the [TiO]:[KOH]:[KNO] weight ratio in the mixture used for the synthesis, increasing with [KNO] in the order of PPT (30:30:40) < PPT (30:50:20) < PPT (30:70:0). The obtained results are explained by increased [Ti] in the PPT structure (XPS data), which is grown in this order from 0 to 4.

Structural Features and Water Resistance of Glass-Matrix Composites in a System of RNO-KHSO-PO Containing Different Additives.

Low-temperature (350 °C) vitrification in a KNO-NaNO-KHSO-NHHPO system, containing various additives to improve the chemical durability of the obtained material, was investigated. It was shown that a glass-forming system with 4.2-8.

Intercalation Effects on the Dielectric Properties of PVDF/TiCT MXene Nanocomposites.

In this study, we report the effect of intercalation of dimethyl sulfoxide (DMSO) and urea molecules into the interlayer space of TiCT MXene on the dielectric properties of poly(vinylidene fluoride) (PVDF)/MXene polymer nanocomposites. MXenes were obtained by a simple hydrothermal method using TiAlC and a mixture of HCl and KF, and they were then intercalated with DMSO and urea molecules to improve the exfoliation of the layers. Then, nanocomposites based on a PVDF matrix loading of 5-30 wt.

Permittivity and Dielectric Loss Balance of PVDF/KFeTiO/MWCNT Three-Phase Composites.

New three-phase composites, destined for application as dielectrics in the manufacturing of passive elements of flexible electronics, and based on polymer (PVDF) matrix filled with powdered ceramics of the hollandite-like (KFTO(H)) structure (5.0; 7.5; 15; 30 vol.

Carbon Modification of KFeTiO Nanoparticles to Optimize the Dielectric Properties of PTFE-Based Composites.

In this work, polymer matrix composites with the compositions PTFE/KFTO(H) and PTFE/KFTO(H)@CB and with filler volume fractions of 2.5, 5.0, 7.

Data on the current-voltage dependents of nickel hollow microspheres based thermo-electrochemical in alkaline electrolyte.

Low-grade waste heat harvesting and conversion into electric energy is an important way of renewable energy development and thermo-electrochemical cells are promising devices to solve this problem. In this paper, we report original data on the current density and maximum output power dependents on voltage of the thermos-cells with nickel hollow microspheres electrodes and different electrolyte concentration (from 0.1 to 3.

The Room-Temperature Chemiresistive Properties of Potassium Titanate Whiskers versus Organic Vapors.

The development of portable gas-sensing units implies a special care of their power efficiency, which is often approached by operation at room temperature. This issue primarily appeals to a choice of suitable materials whose functional properties are sensitive toward gas vapors at these conditions. While the gas sensitivity is nowadays advanced by employing the materials at nano-dimensional domain, the room temperature operation might be targeted via the application of layered solid-state electrolytes, like titanates.

Resonant scattering and absorption in the titanate-based nanoplatelet dispersions in near ultraviolet region.

Extinction enhancement and nonlinear near-resonant absorption of potassium polytitanate nanoplatelets were experimentally studied in the near-UV region. Phenomenological models such as the one-oscillator Lorentz model for dielectric function and the two-level model with the depleted ground state were used to interpret the experimental data. The introduced model parameters demonstrate the adequately high sensitivity to variations in nanoplatelet morphology and chemical environment.