Comparing measured and modelled PFOS concentrations in a UK freshwater catchment and estimating emission rates.

The lifecycle, sources and fate of perfluorooctane sulfonate (PFOS) continue to generate scientific and political interest, particularly since PFOS was listed by the Stockholm Convention and largely restricted in Europe. It continues to be detected in aquatic environments, with only limited studies into the on-going sources. This paper explores PFOS emissions discharged by the general population into a small catchment comprising two rivers in the UK.

Estimating the aquatic emissions and fate of perfluorooctane sulfonate (PFOS) into the river Rhine.

The sources, distribution, levels and sinks of perfluorooctane sulfonate (PFOS) estimated to be released from areas of high population density, have been explored using the river Rhine as a case study. A comparison between modelled and measured data is presented, along with analysis of the importance of PFOS sorption in riverine systems. PFOS releases into the Rhine were estimated to be 325-690 kg/yr based on per capita emission rates of 27-57 μg day(-1) from a population of 33 million living within a 50 km zone either side of the river.

A first global production, emission, and environmental inventory for perfluorooctane sulfonate.

This study makes a new estimate of the global historical production for perfluorooctane sulfonyl fluoride (POSF), and then focuses on producing a first estimate of the global historical environmental releases of perfluorooctane sulfonate (PFOS). The total historical worldwide production of POSF was estimated to be 96,000 t (or 122,500 t, including unusable wastes) between 1970-2002, with an estimated global release of 45,250 t to air and water between 1970-2012 from direct (manufacture, use, and consumer products) and indirect (PFOS precursors and/or impurities) sources. Estimates indicate that direct emissions from POSF-derived products are the major source to the environment resulting in releases of 450-2700 t PFOS into wastewater streams, primarily through losses from stain repellent treated carpets, waterproof apparel, and aqueous fire fighting foams.