Rheological design of thickened alcohol-based hand rubs.

The handleability and sensory perception of hand sanitisers by consumers affect the hygiene outcome. Spillage may result in under-dosing and poor sensory properties can lead to under-utilisation. We first propose four principles (low runoff, spreadability, smoothness and non-stickiness) for designing the rheology of thickened alcohol-based hand rubs with acceptable handleability and hand feel.

Celebrating Soft Matter's 10th Anniversary: Simplicity in complexity--towards a soft matter physics of caramel.

Caramel is a mixture of sugars, milk proteins, fat and water cooked at high temperatures to initiate Maillard reactions. We study caramels as 'active emulsion-filled protein gels', in which fat droplets are chemically-bonded to a background gel matrix of cross-linked proteins in a concentrated aqueous sugar solution. We delimit a 'caramel region' in composition space.

The mechanism of lowering cholesterol absorption by calcium studied by using an in vitro digestion model.

Studies in humans show that a calcium-enriched diet leads to lower cholesterol in blood serum. This phenomenon is usually explained in the literature with a reduced cholesterol absorption in the small intestine. Our study aims to clarify the effect of calcium on the solubilisation of cholesterol and fatty acid in the dietary mixed micelles (DMM), viz.

In vitro study of triglyceride lipolysis and phase distribution of the reaction products and cholesterol: effects of calcium and bicarbonate.

We describe a relatively simple in vitro model for triglyceride (TG) lipolysis which mimics closely the conditions in the human stomach and small intestine. The main model advantages are: (1) as in vivo, sodium bicarbonate is used for buffering; (2) the pH-profile in the small intestine is closely matched; (3) the experimental procedure does not include complex equipment. To test its performance, the proposed in vitro model is applied to quantify the effects of Ca(2+), pH, and bicarbonate on the degree of TG lipolysis and on the solubilization of the lipolysis products and cholesterol in the aqueous phase.

Effects of emulsifier charge and concentration on pancreatic lipolysis: 2. Interplay of emulsifiers and biles.

As a direct continuation of the first part of our in vitro study (Vinarov et al., Langmuir 2012, 28, 8127), here we investigate the effects of emulsifier type and concentration on the degree of triglyceride lipolysis, in the presence of bile salts. Three types of surfactants are tested as emulsifiers: anionic, nonionic, and cationic.

Effects of emulsifier charge and concentration on pancreatic lipolysis. 1. In the absence of bile salts.

An in vitro study is performed with sunflower oil-in-water emulsions to clarify the effects of type of used emulsifier, its concentration, and reaction time on the degree of oil lipolysis, α. Anionic, nonionic, and cationic surfactants are studied as emulsifiers. For all systems, three regions are observed when surfactant concentration is scaled with the critical micelle concentration, C(S)/cmc: (1) At C(S) < cmc, α ≈ 0.

Interfacial layers from the protein HFBII hydrophobin: dynamic surface tension, dilatational elasticity and relaxation times.

The pendant-drop method (with drop-shape analysis) and Langmuir trough are applied to investigate the characteristic relaxation times and elasticity of interfacial layers from the protein HFBII hydrophobin. Such layers undergo a transition from fluid to elastic solid films. The transition is detected as an increase in the error of the fit of the pendant-drop profile by means of the Laplace equation of capillarity.

Surface shear rheology of adsorption layers from the protein HFBII hydrophobin: effect of added β-casein.

The surface shear rheology of hydrophobin HFBII adsorption layers is studied in angle-ramp/relaxation regime by means of a rotational rheometer. The behavior of the system is investigated at different shear rates and concentrations of added β-casein. In angle-ramp regime, the experimental data comply with the Maxwell model of viscoelastic behavior.

The metastable states of foam films containing electrically charged micelles or particles: experiment and quantitative interpretation.

The stepwise thinning (stratification) of liquid films containing electrically charged colloidal particles (in our case - surfactant micelles) is investigated. Most of the results are applicable also to films from nanoparticle suspensions. The aim is to achieve agreement between theory and experiment, and to better understand the physical reasons for this phenomenon.

Self-assembled bilayers from the protein HFBII hydrophobin: nature of the adhesion energy.

The hydrophobins are a class of amphiphilic proteins which spontaneously adsorb at the air/water interface and form elastic membranes of high mechanical strength as compared to other proteins. The mechanism of hydrophobin adhesion is of interest for fungal biology and for various applications in electronics, medicine, and food industry. We established that the drainage of free foam films formed from HFBII hydrophobin solutions ends with the appearance of a 6 nm thick film, which consists of two layers of protein molecules, that is, it is a self-assembled bilayer (S-bilayer), with hydrophilic domains pointing inward and hydrophobic domains pointing outward.

Unique properties of bubbles and foam films stabilized by HFBII hydrophobin.

The HFBII hydrophobin is an amphiphilic protein that can irreversibly adsorb at the air/water interface. The formed protein monolayers can reach a state of two-dimensional elastic solid that exhibits a high mechanical strength as compared to adsorption layers of typical amphiphilic proteins. Bubbles formed in HFBII solutions preserve the nonspherical shape they had at the moment of solidification of their surfaces.

Method for analysis of the composition of acid soaps by electrolytic conductivity measurements.

Here, we propose a method for determining the stoichiometry of acid-soap crystallites. The method is based on dissolving the crystallites in water at an appropriate working temperature, followed by measurement of the electrolytic conductivity of the obtained solutions. The working temperature is chosen in such a way that the only precipitate in the solutions is that of carboxylic acid, whereas the carboxylate salt is dissociated, and its content in the dissolved crystals determines the solution's conductivity.

Interfacial polygonal nanopatterning of stable microbubbles.

Micrometer-sized bubbles are unstable and therefore difficult to make and store for substantial lengths of time. Short-term stabilization is achieved by the addition of amphiphilic molecules, which reduce the driving force for dissolution. When these molecules crystallize on the air/liquid interface, the lifetime of individual bubbles may extend over a few months.

The colloid structural forces as a tool for particle characterization and control of dispersion stability.

Knowing the size and interactions of colloid particles, one can predict the stepwise thickness transitions and the contact angles of particle-containing liquid films. Here, we consider the inverse problem, viz. how to determine the particle properties by measurements with liquid films.

Role of the counterions on the adsorption of ionic surfactants.

A theory accounting for the effect of the counterions on the adsorption constant, K, is proposed. The experimental values of K were determined by using surface and interfacial tension isotherms measured by us or available in the literature. By accounting for the adsorption energy u 0 of the counterion, a generalization of Gouy equation and a modified expression for the adsorption constant, K, are derived.

Acoustical observation of bubble oscillations induced by bubble popping.

Acoustic measurements of aqueous foams show three distinct radiation mechanisms that contribute to the sound pressure field: oscillations of a bubble surface that precede popping due to the instability of thin liquid film, impulsive radiation due to bursts of bubbles, and oscillations from neighboring bubbles excited by a burst bubble. The movies captured by a fast camera confirm that the bubbles adjacent to a breaking bubble oscillate under the influence of the pressure generated by the burst bubble. The spectra of resulting transient sounds fall in the range of 2-8 kHz and those from bubble oscillations correlate well with the bubble size.

Effect of the precipitation of neutral-soap, acid-soap, and alkanoic acid crystallites on the bulk pH and surface tension of soap solutions.

The natural pH of sodium dodecanoate (laurate), NaL, and sodium tetradecanoate (myristate), NaMy, solutions is measured as a function of the surfactant concentrations at 25 degrees C, and at several fixed NaCl concentrations. Surface tension isotherms are also obtained. Depending on the surfactant concentration, the investigated solutions contain precipitates of alkanoic acid, neutral soap, and acid soaps.

Disjoining pressure of thin films stabilized by nonionic surfactants.

In this article an attempt is made to derive a comprehensive theory of the disjoining pressure of thin liquid films, stabilized by low molecular nonionic surfactants. We accounted for effects playing a role in the case of surfactants with spherical hydrophilic heads: (i) The thermal fluctuations of the adsorbed surfactant molecules, due to the fact that the energy of adsorption of a -CH(2)- group is approximately equal to the average thermal energy k(B)T; (ii) The contribution of the collisions between molecules adsorbed on different surfaces; (iii) The restriction imposed on the fluctuation of the molecules by the presence of a second surface situated at a small distance h from the interface where the molecules are adsorbed; (iv) The volume of the hydrophilic heads, which expels part of the water molecules from the film region; (v) The equilibrium between the molecules adsorbed at the film surfaces and at the menisci surrounding the film. The adsorption on the film surfaces has two main effects.

Maximum bubble pressure method: Universal surface age and transport mechanisms in surfactant solutions.

Here, based on the theoretical analysis of results for two ionic surfactants, sodium dodecyl sulfate (SDS) and dodecyl trimethylammonium bromide (DTAB), we develop a new approach for quantitative interpretation of data from the maximum bubble pressure method. A given tensiometer is characterized by an apparatus function, A(t), and by an apparatus constant. The former represents the time dependence of the bubble surface area, whereas the latter is expressed through integrals of A(t).

Influence of electrolytes on the dynamic surface tension of ionic surfactant solutions: expanding and immobile interfaces.

Here, we derive analytical asymptotic expressions for the dynamic surface tension of ionic surfactant solutions in the general case of nonstationary interfacial expansion. Because the diffusion layer is much wider than the electric double layer, the equations contain a small parameter. The resulting perturbation problem is singular and it is solved by means of the method of matched asymptotic expansions.

Adsorption and structure of the adsorbed layer of ionic surfactants.

Our goal in this study was to investigate theoretically and experimentally the adsorption of ionic surfactants and the role of different factors in the mechanism of adsorption, the adsorption parameters and the structure of the adsorbed layer. We used available literature data for the interfacial tension, sigma, vs. concentration, C(s), for sodium dodecyl sulfate (SDS) in three representative systems with Air/Water (A/W), Oil/Water (O/W) and Oil/Water + 0.

Interfacial rheology of adsorbed layers with surface reaction: on the origin of the dilatational surface viscosity.

A theoretical study of the phenomena, occurring in an adsorbed layer, subject to small dilatational perturbations was carried out. Two main processes, provoked by the perturbations (surface reaction and surfactant transport onto the surface) were considered. The reaction was described by means of the reaction coordinate.