Phys Rev E Stat Nonlin Soft Matter Phys
May 2009
We propose a convenient formulation of elemental transport coefficients in chemically reacting and plasma flows locally approaching thermodynamic equilibrium. A set of transport coefficients for elemental diffusion velocities, heat flux, and electric current is introduced. These coefficients relate the transport fluxes with the electric field and with the spatial gradients of elemental fractions, pressure, and temperature.
View Article and Find Full Text PDFPhys Rev E Stat Nonlin Soft Matter Phys
December 2008
Chemical derivatives are used in the mathematical modeling of transport phenomena in equilibrium plasma flows when chemical element diffusion and mixing or demixing effects are accounted for. They measure the variation of mixture chemical composition in response to changes in element fractions, pressure, or temperature. Currently, these quantities are calculated numerically, using finite differences.
View Article and Find Full Text PDF