Synthesis of enantiomerically pure anti-1,2-diaryl and syn-1,2-alkylaryl vic-selenoamines.

Phenylselenyl benzylcarbanion stabilized by an (S)-2-p-tolylsulfinyl group evolves in a highly stereoselective way in the reactions with (S)-N-(p-tolylsulfinyl)imines at -98 °C affording diastereomerically pure 1,2-selenoamino derivatives in good yields. The syn or anti relationship of the obtained compounds depends on the alkyl or aryl character of the imine. They are easily transformed into enantiomerically pure (1R,2S)-1-aryl[or (1S,2S)-1-alkyl]-2-(phenylseleno)-2-phenylethylamines by reaction with t-BuLi and subsequent methanolysis of the generated sulfinamide derivatives with TFA.

Synthesis and stereoselective functionalization of silylated heterocycles as a new class of formyl anion equivalents.

The fluoride ion-induced reactivity of a series of silyl heterocycles leads to the generation of nucleophilic species capable of interacting with electrophiles, thus disclosing new classes of formyl and acyl anion synthons. Moreover, when reacting stereodefined molecules, the stereoinformation of the reacting carbon-silicon bond is transferred to the newly formed carbon-carbon bond, suggesting possible applications in stereoselective synthesis. Thus, silyl dithiolanes, oxathiolanes, dioxolanes, thiazolidines and oxazolidines can be efficiently and stereoselectively functionalized under fluoride ion conditions in the presence of electrophiles.

Growth characteristics of Rhodopseudomonas palustris cultured outdoors, in an underwater tubular photobioreactor, and investigation on photosynthetic efficiency.

The underwater tubular photobioreactor is a fully controlled outdoor system to study photosynthetic bacteria. Before growing bacteria cells outdoors, two modified van Niel medium (vN-A, vN-B) were tested under artificial light. During exponential growth, the specific growth rates were 0.

Different Pathways in the Base-Promoted Isomerization of Benzyl Oxiranyl Ethers.

The base-promoted isomerization of benzyl oxiranyl ethers was investigated. In particular it was shown that the reaction may proceed toward two main regioisomeric products: a benzyl vinyl ether or a 2-aryl-3-(hydroxyalkyl)oxetane, depending on subtle variations in the substitution on the phenyl ring. Disubstituted oxetanes were obtained in a stereoselective manner, thus providing a good entry to this class of synthetically useful compounds.