Nitrite Reduction with HS/Thiol Mediated by Cobalt and Manganese Porphyrins in the Solid State.

The endogenous reduction of nitrite to nitrosyl is drawing increasing attention as a protective mechanism against hypoxic injury in mammalian physiology and as an alternative source of NO, which is involved in a wide variety of biological activities. Thus, chemical mechanisms for this transformation, which are mediated by metallo proteins, are of considerable interest. The study described here examines the reactions of the biomimetic models Co(TTP)(NO) (TTP = meso-tetratolylporphyrinato dianion) and Mn(TPP)(ONO) (TPP = meso-tetraphenyl-porphyrinato dianion) in sublimated solid films with hydrogen sulfide (HS) and with ethanethiol (EtSH) at various temperatures from 77 K to room temperature using in situ infrared and optical spectroscopy.

Wild Species from the Family Apiaceae, Traditionally Used as Food in Some Mediterranean Countries.

Mediterranean countries are a cauldron of cultural exchange, with a strong emphasis on wild plants in cuisine traditions. Many of these plants belong to the family Apiaceae. The common climate determines the common range of distribution.

Reading tea leaves worldwide: Decoupled drivers of initial litter decomposition mass-loss rate and stabilization.

The breakdown of plant material fuels soil functioning and biodiversity. Currently, process understanding of global decomposition patterns and the drivers of such patterns are hampered by the lack of coherent large-scale datasets. We buried 36,000 individual litterbags (tea bags) worldwide and found an overall negative correlation between initial mass-loss rates and stabilization factors of plant-derived carbon, using the Tea Bag Index (TBI).

Recurrence After Colectomy for Locally Advanced Colon Cancer: Experience from a Developing Country.

Unlabelled: Risk factors for disease recurrence following curative resection for locally advanced colon cancer (LACC) remain unclear as conflicting results have been reported in the literature. The aim of this study was to examine these factors in the setting of developing country's health care system affected by limited accessibility to the multimodal cancer treatment. Patients who had undergone curative colon resection for LACC between 2004 and 2018 were included.

Confocal Raman microscope with versatile dual polarization snapshot acquisition.

In this paper we propose a new strategy towards simultaneous co- and cross-polarized measurements of Raman spectra in a confocal microscope. One of the advantages of this strategy is that it is immune to polarization-dependent efficiency of diffraction gratings. It is shown via linear angle-resolved and circular polarization measurements that the accuracy of these snapshot polarization measurements on solid and liquid samples are in good agreement with available models and data.

Experimental focusing shocklike dynamics in a nonlocal optical stochastic Kerr medium.

We experimentally study the propagating of an optical intensity jump discontinuity in a nonlocal stochastic Kerr focusing nematic liquid crystal cell. We show both theoretically and experimentally that nonlocality opens a route towards beam steering in our system. Indeed, the discontinuity trajectory follows a curve that bends with the injected power.

Technique of laryngotracheal resection in subglottic stenosis.

Cervical stenosis of the trachea caused by tracheotomy, tumor or induced by inflammatory disease can be treated by resection and anastomosis with good early and long-term results. Involvement of the ring cartilage makes the procedure technical demanding and increases the risk of morbidity. We describe our technique of laryngotracheal resection and reconstruction and compare the perioperative results with standard trachea resection.

Co-designed annular binary phase masks for depth-of-field extension in single-molecule localization microscopy.

Single-molecule localization microscopy has become a prominent approach to study structural and dynamic arrangements of nanometric objects well beyond the diffraction limit. To maximize localization precision, high numerical aperture objectives must be used; however, this inherently strongly limits the depth-of-field (DoF) of the microscope images. In this work, we present a framework inspired by "optical co-design" to optimize and benchmark phase masks, which, when placed in the exit pupil of the microscope objective, can extend the DoF in the realistic context of single fluorescent molecule detection.

An application to support COVID-19 occupational health and patient tracking at a Veterans Affairs medical center.

Objective: Reducing risk of coronavirus disease 2019 (COVID-19) infection among healthcare personnel requires a robust occupational health response involving multiple disciplines. We describe a flexible informatics solution to enable such coordination, and we make it available as open-source software.

Materials And Methods: We developed a stand-alone application that integrates data from several sources, including electronic health record data and data captured outside the electronic health record.

Standard and multivisceral colectomy in locally advanced colon cancer.

Background Management of locally advanced colon cancer (LACC) is challenging. Surgery is the mainstay of the treatment, yet its outcomes remain unclear, especially in the setting of multivisceral resections. The aim of the study was to examine the outcomes of standard and multivisceral colectomy in patients with LACC.

High-throughput protein precipitation method with 96-well plate for determination of doxepin and nordoxepin in human plasma using LC-MS/MS.

The aim of this study was to establish a high-throughput and sensitive LC-MS/MS method for the determination of doxepin and its major active metabolite nordoxepin in human plasma. It has been designed for bioequivalence study for formulations containing 25 mg of doxepin. Doxepin and nordoxepin were extracted from human plasma samples by protein precipitation with acetonitrile by using protein precipitation 96-well plates.

Protein precipitation method for determination of clobazam and N-desmethylclobazam in human plasma by LC-MS/MS.

A protein precipitation method for the determination of clobazam (CLB) and its major active metabolite N-desmethylclobazam (N-CLB) in human plasma by liquid chromatography tandem mass spectrometry (LC-MS/MS) was established. CLB and N-CLB were extracted from human plasma samples by protein precipitation with methanol. Analyte separation was done using a Phenomenex Kinetex™ Biphenyl (50 × 2.

Laparoscopic and open repair for perforated duodenal ulcer: single-center experience.

Introduction: Perforation is a dangerous complication of peptic ulcer disease and requires emergency surgical treatment. In recent decades laparoscopic repair of duodenal perforation has been widely used in emergency abdominal surgery.

Aim: To analyze laparoscopic and open surgical treatment of 120 consecutive patients with perforated duodenal ulcer.

Chiral Optical Stern-Gerlach Newtonian Experiment.

We report on a chiral optical Stern-Gerlach experiment where chiral liquid crystal microspheres are selectively displaced by means of optical forces arising from optical helicity gradients. The present Newtonian experimental demonstration of an effect predicted at molecular scale [New J. Phys.

[Laryngo-Tracheal Resection as an Alternative to Permanent Tracheostomy].

Introduction:  Cervical stenosis of the trachea caused by tracheotomy, tumor or without defined reason (idiopathic) can be treated by resection and anastomosis with good early and long-term results. Involvement of the ring cartilage makes the procedure technically demanding and increases the risk of morbidity. We describe our technique of laryngotracheal resection and reconstruction and compare the perioperative results with standard tracheal resection.

The Global Naturalized Alien Flora (GloNAF) database.

This dataset provides the Global Naturalized Alien Flora (GloNAF) database, version 1.2. GloNAF represents a data compendium on the occurrence and identity of naturalized alien vascular plant taxa across geographic regions (e.

High-charge and multiple-star vortex coronagraphy from stacked vector vortex phase masks.

Optical vortex phase masks are now installed at many ground-based large telescopes for high-contrast astronomical imaging. To date, such instrumental advances have been restricted to the use of helical phase masks of the lowest even order, while future giant telescopes will require high-order masks. Here we propose a single-stage on-axis scheme to create high-order vortex coronagraphs based on second-order vortex phase masks.

Airway Management by Laryngeal Mask Airways for Cervical Tracheal Resection and Reconstruction: A Single-Center Retrospective Analysis.

Background: Supraglottic airway devices (SADs) may have advantages over endotracheal intubation for tracheal resection and reconstruction in cases of severe and proximally located subglottic stenosis. This retrospective case series examines the feasibility of using SADs as a novel approach to airway management in tracheal resections.

Methods: All patients who were managed with SADs for cervical tracheal resection and reconstruction during the study period (2010-2015) in our university hospital were included.

[COMPLICATIONS OF PREGNANCY, RESULTING FROM ASSISTED REPRODUCTIVE TECHNOLOGY].

When pregnancy occurs as a result of assisted reproductive technologies (ART), there are more chances of developing complications and adverse outcomes for the mother and fetus compared to spontaneous pregnancies. Taking into account the noted features, the purpose of our study was to determine the nature of the complications of induced pregnancy and their frequency, depending on the causes of infertility. Under our supervision were 86 women with induced single-pregnancy.

Multiple-Star System Adaptive Vortex Coronagraphy Using a Liquid Crystal Light Valve.

We propose the development of a high-contrast imaging technique enabling the simultaneous and selective nulling of several light sources. This is done by realizing a reconfigurable multiple-vortex phase mask made of a liquid crystal thin film on which local topological features can be addressed electro-optically. The method is illustrated by reporting on a triple-star optical vortex coronagraphy laboratory demonstration, which can be easily extended to higher multiplicity.

Self-eclipsing: alignment-free vortex coronagraphy.

We report on a self-induced strategy to achieve high-contrast optical imaging, without the need for any man-made optical masks, which relies on the self-induced spin-to-orbital angular momentum conversion phenomenon. This is experimentally demonstrated by realizing a laboratory demonstration of self-eclipsing of a light source following the generation of a self-adapted vectorial optical vortex transmission mask. The proposed concept, namely the realization of an alignment-free optical vortex coronagraph, may inspire the development of future generations of smart astronomical imaging instruments.

A Unique Historical Case to Understand the Present Sustainable Development.

Every innovation seeks to become a profitable business, with this considered to be the engine for economic prosperity. When an innovation is revolutionary, its long-term consequences can be revolutionary too. The Haber-Bosh process for ammonia synthesis is arguably the twentieth century's most significant innovation, and its importance to global food production and its impact on the environment are not expected to diminish over the coming decades.