Comprehensive characterization of lignins in the context of their valorization: A combination of NMR/2D-COS IR spectroscopy.

The widespread development of lignin valorization is hindered by a number of challenges. In particular, efficient valorization necessitates comprehensive characterization of initial lignins. In this work, the structural features of lignins from birch wood (Bétula péndula), obtained by various methods of hard and mild fractionation of biomass: hydrolysis (Hyd-L), kraft (Kraft-L), soda (Soda-L), and soda-ethanol (SodaEt-L) processes, as well as organosolv processes with dioxane (MWL, DL) and dimethyl sulfoxide (DMSO-L) have been comprehensively studied.

Optimization of Approaches to Analysis of Lignin by Thermal Decomposition.

The ratio of monomeric units is one of the main characteristics of lignin, which affects the possibilities and strategies for further processing. Pyrolytic and thermal desorption decomposition of lignins followed by mass detection of macromolecule fragments are the most common methods for determining the amount of lignin structural units. Two methods of thermal decomposition of lignin were studied: thermal desorption-GC/MS (TD-GC/MS) and pyrolysis-GC/MS (Py-GC/MS).

Data of polycyclic aromatic hydrocarbons concentration in the Siberian Arctic seas sediments.

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the most dangerous persistent organic pollutants in the Arctic. They have different sources and pathways of entering in to the environment. Because of their lipophilic properties, PAHs can easily accumulate in marine sediments.

Polycyclic aromatic hydrocarbons in the Siberian Arctic seas sediments.

Polycyclic Aromatic Hydrocarbons (PAHs) are among the main persistent organic pollutants in the Arcticwhich enter the polar region from lower latitudes by air transport and ocean currents and accumulate in marine sediments. This work represents the first study in 25 years of the least studied and hard-to-reach areas of Siberian arctic seas. Sixteen priority PAHs as well as 1- and 2-methylnaphthalenes were analyzed by gas chromatography - tandem mass spectrometry in the twenty-four sediment samples taken from Kara, Laptev and East Siberian Seas in October 2020.

Assessment of seasonal variability of input of microplastics from the Northern Dvina River to the Arctic Ocean.

Northern Dvina River is one of the largest rivers in the European Arctic flowing into the White Sea through the populated regions with developed industry. Floating plastics include microplastics (0.5-5 mm) and mesoplastics (5-25 mm) were observed on seasonal variations in the Northern Dvina River mouth.

Analysis of the functional group composition of the spruce and birch phloem lignin.

In this article, the functional group composition of the spruce (Pícea ábies) and birch (Bétula péndula) phloem lignin is described. The features of the chemical structure were studied by analyzing dioxane lignin using the elemental analysis, UV-Vis, FT-IR, and 1D NMR spectroscopy. For comparison, samples of xylem dioxane lignin isolated from the corresponding wood species were also analyzed.

Comprehensive analysis of the chemical structure of lignin from raspberry stalks (Rubus idaeus L.).

Lignins of non-woody fast-growing plants cause high interest in recent time as a potential source of raw materials for biorefining. Studying of the lignin structure in shrubs will allow obtaining the information about processes of biosynthesis of these plants and developing methods of their delignification for bioprocessing industry. We studied the structure of raspberry dioxane lignin (Rubus idaeus L.

Structural characterization of the lignin from Saxifraga (Saxifraga oppositifolia L.) stems.

As a renewable source of unique aromatic compounds, lignin attracts the attention of many researchers. However, for its successful application, it is necessary to have a clear and accurate idea of its chemical structure. Therefore, it is necessary to expand knowledge about the structure of lignins of various nature using the informative analytical methods.