3D imaging photocatalytically degraded micro- and nanoplastics.

Microplastics (MPs) and nanoplastics have been an emerging global concern, with hazardous effects on plant, animal, and human health. Their small size makes it easier for them to spread to various ecosystems and enter the food chain; they are already widely found in aqueous environments and within aquatic life, and have even been found within humans. Much research has gone into understanding micro-/nanoplastic sources and environmental fate, but less work has been done to understand their degradation.

Rippling Colloidal Polyelectrolyte Complex for Customized Fingerprints with High Tactile Perception.

Fingerprints possess wide applications in personal identification, tactile perception, access control, and anti-counterfeiting. However, latent fingerprints are usually left on touched surfaces, leading to the leakage of personal information. Furthermore, tactile perception greatly decreases when fingerprints are covered by gloves.

A critical review of microplastic degradation and material flow analysis towards a circular economy.

The resilience and low cost of plastics has made their usage ubiquitous, but is also the cause of their prevalence and longevity as waste. Plastic pollution has become a great concern to the health and wellbeing of ecosystems around the world; microplastics are a particular threat, due to their high mobility, ease of ingestion by wildlife, and ability to adsorb and carry toxic contaminants. Material flow analysis has been widely applied to examine stocks and flows of materials in other industries, and has more recently been applied to plastics to examine areas where waste can reach the environment.

Imparting conformational memory for material adhesion.

Adhesion between similar and dissimilar materials is essential to many biological systems and synthetic materials, devices, and machines. Since the inception of adhesion science more than five decades ago, adhesion to a surface has long been recognized as beyond two-dimensional. Similarly, molecular conformation - the three-dimensional arrangement of atoms in a molecule - is ubiquitous in biology and fundamental to the binding of biomolecules.

Polymer Binders: Characterization and Development toward Aqueous Electrode Fabrication for Sustainability.

Binders play an important role in electrode processing for energy storage systems. While conventional binders often require hazardous and costly organic solvents, there has been increasing development toward greener and less expensive binders, with a focus on those that can be processed in aqueous conditions. Due to their functional groups, many of these aqueous binders offer further beneficial properties, such as higher adhesion to withstand the large volume changes of several high-capacity electrode materials.

Viscoelastic tribopairs in dry and lubricated sliding friction.

Soft contacts present different tribological responses compared to stiff materials, especially when soft materials exhibit viscoelastic behaviour, as viscoelastic materials have intermediate mechanical properties between viscous liquids and elastic solids. In this work, we investigated the influence of viscoelasticity of soft materials on sliding friction in dry and lubricated conditions. To achieve this, soft tribopairs with varying viscoelasticity were obtained by tuning the weight ratios of polydimethylsiloxane (PDMS) base and curing agent.

Catechol-functionalized hydrogels: biomimetic design, adhesion mechanism, and biomedical applications.

Hydrogels are a unique class of polymeric materials that possess an interconnected porous network across various length scales from nano- to macroscopic dimensions and exhibit remarkable structure-derived properties, including high surface area, an accommodating matrix, inherent flexibility, controllable mechanical strength, and excellent biocompatibility. Strong and robust adhesion between hydrogels and substrates is highly desirable for their integration into and subsequent performance in biomedical devices and systems. However, the adhesive behavior of hydrogels is severely weakened by the large amount of water that interacts with the adhesive groups reducing the interfacial interactions.

A hybrid material that reversibly switches between two stable solid states.

Most types of solid matter have a single stable solid state for a particular set of conditions. Nonetheless, materials with distinct, interchangeable solid states would be advantageous for several technological applications. Here, we describe a material composed of a polymer impregnated with a supercooled salt solution, termed as sal-gel, that assumes two distinct but stable and reversible solid states under the same conditions for a range of temperatures (-90 to 58 °C) and pressure.

Underwater Contact Behavior of Alginate and Catechol-Conjugated Alginate Hydrogel Beads.

Modifying hydrogels with catechol functionality is a promising approach for improving their mechanical and interfacial properties in water, particularly in biological environments. However, the effects of this modification on hydrogels' contact behavior with soft tissues are not well-studied due to the complexity of hydrogels and lack of suitable techniques to probe this behavior. In addition, modification can alter the mechanical properties of hydrogels, resulting in consequences for adhesive strength as well.