Publications by authors named "Alejandro Morales-Cantero"

Article Synopsis
  • Researchers have struggled to fully understand cement dissolution and precipitation processes for the past century due to limitations in imaging techniques.
  • The study utilizes near-field ptychographic nanotomography to visualize the hydration of Portland cement, revealing a porous C-S-H gel shell forming around alite grains within 19 hours.
  • It was found that small alite grains dissolve approximately four times faster than larger ones, and the work aims to further explore these processes with advanced imaging techniques, including the effects of additives like accelerators and superplasticizers.
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Reducing cement CO footprint is a societal need. This is being achieved mainly by replacing an increasing amount of Portland clinker by supplementary cementitious materials. However, this comes at a price: lower mechanical strengths at early ages due to slow pozzolanic reaction(s).

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The acceleration of very early age cement hydration by C-S-H seeding is getting attention from scholars and field applications because the enhanced early age features do not compromise later age performances. This acceleration could be beneficial for several low-CO cements as a general drawback is usually the low very early age mechanical strengths. However, the mechanistic understanding of this acceleration in commercial cements is not complete.

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The effect of superplasticiser, borax and the water-to-cement ratio on BYF hydration and mechanical strengths has been studied. Two laboratory-scale BYF cements-st-BYF (with β-CS and orthorhombic CAS¯) and borax-activated B-BYF (with α'-CS and pseudo-cubic CAS¯)-have been used, and both show similar particle size distribution. The addition of superplasticiser and externally added borax to BYF pastes has been optimised through rheological measurements.

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